List-$I$ contains metal species and List-$II$ contains their properties.
List-$I$ List-$II$
$I$. $[Cr(CN)_6]^{4-}$ $P$. $t_{2g}$ orbitals contain $4$ electrons
$II$. $[RuCl_6]^{2-}$ $Q$. $\mu$ (spin-only) $= 4.9 \ BM$
$III$. $[Cr(H_2O)_6]^{2+}$ $R$. low spin complex ion
$IV$. $[Fe(H_2O)_6]^{2+}$ $S$. metal ion in $4+$ oxidation state
$T$. $d^4$ species

[Given: Atomic number of $Cr = 24, Ru = 44, Fe = 26$] Match each metal species in List-$I$ with their properties in List-$II$,and choose the correct option.

  • A
    $I$ $\rightarrow R, T; II$ $\rightarrow P, S; III$ $\rightarrow Q, T; IV$ $\rightarrow P, Q$
  • B
    $I$ $\rightarrow R, S; II$ $\rightarrow P, T; III$ $\rightarrow P, Q; IV$ $\rightarrow Q, T$
  • C
    $I$ $\rightarrow P, R; II$ $\rightarrow R, S; III$ $\rightarrow R, T; IV$ $\rightarrow P, T$
  • D
    $I$ $\rightarrow Q, T; II$ $\rightarrow S, T; III$ $\rightarrow P, T; IV$ $\rightarrow Q, R$

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Magnetic moment (spin only) of an octahedral complex having $CFSE = -0.8 \Delta_0$ and surrounded by weak field ligands can be

Among the statements $(a)-(d)$,the incorrect ones are:
$(a)$ Octahedral $Co(III)$ complexes with strong field ligands have very high magnetic moments.
$(b)$ When $\Delta_{0} < P$,the $d-$electron configuration of $Co(III)$ in an octahedral complex is $t_{2g}^{4} e_{g}^{2}$.
$(c)$ Wavelength of light absorbed by $[Co(en)_{3}]^{3+}$ is lower than that of $[CoF_{6}]^{3-}$.
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Match each coordination compound in List-$I$ with an appropriate pair of characteristics from List-$II$ and select the correct answer using the code given below the lists.
$\{ en = H_2NCH_2CH_2NH_2 \}$; atomic numbers: $\{Ti = 22; Cr = 24; Co = 27; Pt = 78\}$
List-$I$ List-$II$
$P.$ $[Cr(NH_3)_4Cl_2]Cl$ $1.$ Paramagnetic and exhibits ionisation isomerism
$Q.$ $[Ti(H_2O)_5Cl](NO_3)_2$ $2.$ Diamagnetic and exhibits cis-trans isomerism
$R.$ $[Pt(en)(NH_3)_2Cl_2]NO_3$ $3.$ Paramagnetic and exhibits cis-trans isomerism
$S.$ $[Co(NH_3)_4(NO_3)_2]NO_3$ $4.$ Diamagnetic and exhibits ionisation isomerism
Codes: $P, Q, R, S$

The magnetic moment (spin only) of an octahedral complex having $CFSE = -0.8 \Delta_0$ and surrounded by weak field ligands can be:

When potassium iodide is added to an aqueous solution of potassium ferricyanide,a reversible reaction is observed in which a complex $P$ is formed. In a strong acidic medium,the equilibrium shifts completely towards $P$. Addition of zinc chloride to $P$ in a slightly acidic medium results in a sparingly soluble complex $Q$.
$(1)$ The number of moles of potassium iodide required to produce two moles of $P$ is. . .
$(2)$ The number of zinc ions present in the molecular formula of $Q$ is. . . .
Give the answer for $(1)$ and $(2)$.

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