Among the statements $(a)-(d)$,the incorrect ones are:
$(a)$ Octahedral $Co(III)$ complexes with strong field ligands have very high magnetic moments.
$(b)$ When $\Delta_{0} < P$,the $d-$electron configuration of $Co(III)$ in an octahedral complex is $t_{2g}^{4} e_{g}^{2}$.
$(c)$ Wavelength of light absorbed by $[Co(en)_{3}]^{3+}$ is lower than that of $[CoF_{6}]^{3-}$.
$(d)$ If the $\Delta_{0}$ for an octahedral complex of $Co(III)$ is $18,000 \ cm^{-1}$,the $\Delta_{t}$ for its tetrahedral complex with the same ligand will be $16,000 \ cm^{-1}$.

  • A
    $(a)$ and $(b)$ only
  • B
    $(c)$ and $(d)$ only
  • C
    $(b)$ and $(c)$ only
  • D
    $(a)$ and $(d)$ only

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Difficult
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The correct statements from the following are:
$A$. The strength of anionic ligands can be explained by crystal field theory.
$B$. Valence bond theory does not give a quantitative interpretation of kinetic stability of coordination compounds.
$C$. The hybridization involved in the formation of $\left[Ni(CN)_4\right]^{2-}$ complex is $dsp^2$.
$D$. The number of possible isomer$(s)$ of $cis-\left[PtCl_2(en)_2\right]^{2+}$ is one.
Choose the correct answer from the options given below:

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