$100 \ mL$ of $1.5\%(w/v)$ solution of urea has an osmotic pressure of $6.0 \ atm$ and $100 \ mL$ of $3.42\%(w/v)$ solution of cane sugar has an osmotic pressure of $2.4 \ atm$. If the two solutions are mixed,the osmotic pressure of the resulting solution in $atm$ is (Assume that there is no reaction between urea and cane sugar).

$A$ solution of urea in water has a boiling point of $100.18^{\circ} C$. What is the freezing point of the same solution,if $K_{f}$ and $K_{b}$ of water are $1.86$ and $0.52 \ K \ kg \ mol^{-1}$,respectively (in $^{\circ} C$)? (Boiling point of water $= 100^{\circ} C$ )

The difference between the boiling point and freezing point of an aqueous solution of urea containing $10.0 \ kg$ of water is $100.2372 \ ^oC$. How many grams of urea are dissolved in the solution? (Given: $K_b = 0.513 \ K \ kg \ mol^{-1}$,$K_f = 1.86 \ K \ kg \ mol^{-1}$)

Match List-$I$ with List-$II$

List-$I$	List-$II$
$A$. Solution of chloroform and acetone	$I$. Minimum boiling azeotrope
$B$. Solution of ethanol and water	$II$. Dimerizes
$C$. Solution of benzene and toluene	$III$. Maximum boiling azeotrope
$D$. Solution of acetic acid in benzene	$IV$. $\Delta V_{mix}=0$

Choose the correct answer from the options given below $:$

When $1.685 \ g$ of an alkali metal chloride is dissolved in $200 \ g$ water,the boiling point of the solution is measured to be $100.051 \ ^\circ C$. If the ionic solid has a crystal lattice with cation and anion radius $1.70 \ \mathring{A}$ and $1.80 \ \mathring{A}$ respectively,find the edge length of the solid assuming no defect in the crystal. Given: $K_b(H_2O) = 0.51 \ K \ kg \ mol^{-1}$,$N_A = 6 \times 10^{23}$,atomic masses: $[Li = 7, Na = 23, K = 39, Rb = 85.5, Cs = 133, Cl = 35.5]$.

Calculate the osmotic pressure in $atm$ at $0\,^oC$ of a $0.18\, m$ aqueous solution of $KCl$ which has a freezing point of $-0.68\,^oC$. Assume the volume of the solution is equal to the volume of pure water. $(K_f = 1.86\,^oC\, m^{-1})$