$6 \ g$ of a non-volatile,non-electrolyte $X$ dissolved in $100 \ g$ of water freezes at $-0.93^{\circ} C$. The molar mass of $X$ in $g \ mol^{-1}$ is ($K_f$ of $H_2O = 1.86 \ K \ kg \ mol^{-1}$)

Column-$I$ (Various solutions)	Column-$II$ (Freezing point)
$a$. $0.1 \, M \ BaCl_2$ solution	$p$. $271 \, K$
$b$. $0.1 \, M \ NaCl$ solution	$q$. $270 \, K$
$c$. $0.1 \, M \ K_3[Fe(CN)_6]$ solution	$r$. $268 \, K$
$d$. $0.1 \, M \ Al_2(SO_4)_3$ solution	$s$. $269 \, K$

Given: Freezing point of $0.1 \, M$ sucrose solution $= 272 \, K$ and freezing point of water $= 273 \, K$.
Which of the following options shows the correct matches?

$83 \ g$ of ethylene glycol is dissolved in $625 \ g$ of water. The freezing point of the solution is $...... \ K$. (Nearest integer) [Use: Molal freezing point depression constant of water $= 1.86 \ K \ kg \ mol^{-1}$,Freezing point of water $= 273 \ K$,Atomic masses: $C = 12.0 \ u, O = 16.0 \ u, H = 1.0 \ u$]

Which of the following solutions has the highest freezing point?

Molal depression constant $(K_{f})$ is dependent on

The freezing point of a solution containing $10 \ mL$ of non-volatile and non-electrolyte liquid $A$ in $500 \ g$ of water is $-0.413^{\circ} C$. If $K_f$ of water is $1.86 \ K \ kg \ mol^{-1}$ and the molecular weight of $A = 60 \ g \ mol^{-1}$, what is the density of the solution in $g \ mL^{-1}$? (Assume $\Delta_{\text{mix}} V = 0$)