For a spontaneous reaction,determine the values of $\Delta G^o$,equilibrium constant $K$,and $E^o_{cell}$ respectively.

  • A
    $+ve, > 1, +ve$
  • B
    $-ve, > 1, +ve$
  • C
    $+ve, < 1, -ve$
  • D
    $-ve, < 1, -ve$

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Given that $Ni^{2+}/Ni = -0.25 \ V$; $Cu^{2+}/Cu = 0.34 \ V$; $Ag^{+}/Ag = 0.80 \ V$; $Zn^{2+}/Zn = -0.76 \ V$. Which of the following reactions under standard conditions will not take place in the specified direction?

Calculate the equilibrium constant for the reaction: $Cl_{2(g)} + 2I^{-}_{(aq)} \to 2Cl^{-}_{(aq)} + I_{2(s)}$
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Electrolyte$\Lambda_m^\circ$ $(S\text{ cm}^2\text{ mol}^{-1})$
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Chemical reactions involve the interaction of atoms and molecules. $A$ large number of atoms/molecules (approximately $6.023 \times 10^{23}$) are present in a few grams of any chemical compound,varying with their atomic/molecular masses. To handle such large numbers conveniently,the mole concept was introduced. This concept has implications in diverse areas such as analytical chemistry,biochemistry,electrochemistry,and radiochemistry. The following example illustrates a typical case involving a chemical/electrochemical reaction,which requires a clear understanding of the mole concept. $A$ $4.0 \ M$ aqueous solution of $NaCl$ is prepared and $500 \ mL$ of this solution is electrolysed. This leads to the evolution of chlorine gas at one of the electrodes (atomic mass: $Na=23, Hg=200; 1 \ F = 96500 \ C$).
$1.$ The total number of moles of chlorine gas evolved is:
$(A)$ $0.5$ $(B)$ $1.0$ $(C)$ $2.0$ $(D)$ $3.0$
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$(A)$ $200$ $(B)$ $225$ $(C)$ $400$ $(D)$ $446$
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