Given the following thermochemical equations:
$(i) S_{(s)} + \frac{3}{2} O_{2(g)} \rightarrow SO_{3(g)} + 2x \, kcal$
$(ii) SO_{2(g)} + \frac{1}{2} O_{2(g)} \rightarrow SO_{3(g)} + y \, kcal$
Find the heat of formation of $SO_{2(g)}$.

When $50 \ cm^3$ of $0.2 \ N \ H_2SO_4$ is mixed with $50 \ cm^3$ of $1 \ N \ KOH$,the heat liberated is

The reversible expansion of an ideal gas under adiabatic and isothermal conditions is shown in the figure. Which of the following statement$(s)$ is (are) correct?
$(A)$ $T_1 = T_2$
$(B)$ $T_3 > T_1$
$(C)$ $W_{\text{isothermal}} > W_{\text{adiabatic}}$
$(D)$ $\Delta U_{\text{isothermal}} > \Delta U_{\text{adiabatic}}$

Assertion : The increase in internal energy $(\Delta E)$ for the vaporization of one mole of water at $1 \ atm$ and $373 \ K$ is zero.
Reason : For all isothermal processes,$\Delta E = 0$.

Which of the following equations are correct?
$(A)$ $H = U + PV$
$(B)$ $G = H - TS$
$(C)$ $U = q + W$

$1 \ g$ of graphite is burnt in a bomb calorimeter in excess of oxygen at $298 \ K$ and $1 \ atm$ atmospheric pressure according to the equation:
$C \ (graphite) + O_{2(g)} \rightarrow CO_{2(g)}$
During the reaction,the temperature rises from $298 \ K$ to $299 \ K$. If the heat capacity of the bomb calorimeter is $20.7 \ kJ \ K^{-1}$,what is the enthalpy change for the above reaction at $298 \ K$ and $1 \ atm$?