Which of the following has the maximum mass?

For the reaction: $N_{2(g)} + 3H_{2(g)} \rightarrow 2NH_{3(g)}$,$\Delta H = -24 \ \text{kcal}$ at $427 \ ^\circ\text{C}$ and $200 \ \text{atm}$. Calculate the magnitude of the internal energy change ($\Delta U$ in $\text{kcal}$),if $168 \ \text{g}$ of $N_2$ gas and $30 \ \text{g}$ of $H_2$ gas are allowed to react completely ($100\%$ reaction yield) to form $NH_3$ gas at $427 \ ^\circ\text{C}$ and $200 \ \text{atm}$.

Molarity of a $50 \ mL$ $H_2SO_4$ solution is $10.0 \ M$. If the density of the solution is $1.4 \ g/cc$, calculate its molality.

Which is the correct option for $0.1 \ M$,$500 \ mL$ of $AgCl$?

Assume that a human body requires $2500 \, kcal$ of energy each day for metabolic activity and sucrose is the only source of energy,as per the equation $C_{12}H_{22}O_{11(s)} + 12 \, O_{2(g)} \longrightarrow 12 \, CO_{2(g)} + 11 \, H_2O_{(l)};$ $\Delta H = -5.6 \times 10^6 \, J$. (Fill in the blanks) $(a)$ The energy requirement of the human body per day is $.... \, kJ$. $(b)$ The mass of sucrose required to provide this energy is $........ \, g$ and the volume of $CO_2$ (at $STP$) produced is $......... \, litres.$

Rearrange the following ($I$ to $IV$) in the order of increasing masses and choose the correct answer (Atomic mass: $N=14, O=16, Cu=63$).
$I.$ $1$ molecule of oxygen
$II.$ $1$ atom of nitrogen
$III.$ $1 \times 10^{-10} \ g$ molecular weight of oxygen
$IV.$ $1 \times 10^{-10} \ g$ atomic weight of copper