Which ion$(s)$ precipitate when an oxalate solution is added to a mixture of $Ba^{2+}$,$Sr^{2+}$,and $Ca^{2+}$?

An aqueous solution of a salt $X$ turns blood red on treatment with $CNS^{-}$ and blue on treatment with $K_4[Fe(CN)_6]$. $X$ also gives a positive chromyl chloride test. The salt $X$ is

Match the List-$I$ with List-$II$ :

Cations	Group reaction
$P \rightarrow Pb^{2+}, Cu^{2+}$	$(i)$ $H_2S$ gas in presence of dilute $HCl$
$Q \rightarrow Al^{3+}, Fe^{3+}$	$(ii)$ $(NH_4)_2CO_3$ in presence of $NH_4OH$
$R \rightarrow Co^{2+}, Ni^{2+}$	$(iii)$ $NH_4OH$ in presence of $NH_4Cl$
$S \rightarrow Ba^{2+}, Ca^{2+}$	$(iv)$ $H_2S$ in presence of $NH_4OH$

Which mixture can be separated by a concentrated aqueous solution of sodium hydroxide $(NaOH)$?

In the fifth group of qualitative analysis,$(NH_4)_2CO_3$ is added to precipitate out the carbonates. We do not add $Na_2CO_3$ because

Consider the following sequence of reactions:
$M^{2+}(aq.)$ $\xrightarrow{NH_4Cl(s) + (NH_4)_2CO_3 \, sol.} Q \downarrow$ $\xrightarrow[\text{Followed by addition of } (NH_4)_2C_2O_4]{CH_3COOH} R \downarrow$
Which of the following cations can form precipitate $Q$ but does not form precipitate $R$?