Medium
For the reaction $Cl_{2(aq)} + H_2S_{(aq)} \to S_{(s)} + 2H^+_{(aq)} + 2Cl^-_{(aq)}$, the rate law is given by $\text{Rate} = K[Cl_2][H_2S]$. Which of the following mechanisms is consistent with this rate law?
$(A)$ $Cl_2 + H_2S \to H^+ + Cl^- + Cl^+ + HS^-$ (slow); $Cl^+ + HS^- \to H^+ + Cl^- + S$ (fast)
$(B)$ $H_2S \rightleftharpoons H^+ + HS^-$ (fast equilibrium); $Cl_2 + HS^- \to 2Cl^- + H^+ + S$ (slow)
$(A)$ $Cl_2 + H_2S \to H^+ + Cl^- + Cl^+ + HS^-$ (slow); $Cl^+ + HS^- \to H^+ + Cl^- + S$ (fast)
$(B)$ $H_2S \rightleftharpoons H^+ + HS^-$ (fast equilibrium); $Cl_2 + HS^- \to 2Cl^- + H^+ + S$ (slow)
- ANeither $A$ nor $B$
- BOnly $A$
- COnly $B$
- DBoth $A$ and $B$
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Similar Questions
The bromination of acetone that occurs in acid solution is represented by this equation.
$CH_3COCH_{3(aq)} + Br_{2(aq)} \rightarrow CH_3COCH_2Br_{(aq)} + H^+_{(aq)} + Br^-_{(aq)}$
These kinetic data were obtained for given reaction concentrations.
Initial concentrations,$M$
$[CH_3COCH_3]$ $[Br_2]$ $[H^+]$ $0.30$ $0.05$ $0.05$ $0.30$ $0.10$ $0.05$ $0.30$ $0.10$ $0.10$ $0.40$ $0.05$ $0.20$
Initial rate,disappearance of $Br_2, M s^{-1}$
$5.7 \times 10^{-5}, 5.7 \times 10^{-5}, 1.14 \times 10^{-4}, 3.04 \times 10^{-4}$
Based on these data,the rate equation is
$CH_3COCH_{3(aq)} + Br_{2(aq)} \rightarrow CH_3COCH_2Br_{(aq)} + H^+_{(aq)} + Br^-_{(aq)}$
These kinetic data were obtained for given reaction concentrations.
Initial concentrations,$M$
| $[CH_3COCH_3]$ | $[Br_2]$ | $[H^+]$ |
| $0.30$ | $0.05$ | $0.05$ |
| $0.30$ | $0.10$ | $0.05$ |
| $0.30$ | $0.10$ | $0.10$ |
| $0.40$ | $0.05$ | $0.20$ |
Initial rate,disappearance of $Br_2, M s^{-1}$
$5.7 \times 10^{-5}, 5.7 \times 10^{-5}, 1.14 \times 10^{-4}, 3.04 \times 10^{-4}$
Based on these data,the rate equation is
Write the general reaction and its rate law.
Medium
View SolutionFor a reaction $r = k[A][B]^2$,if the concentration of $A$ is doubled,the rate of reaction:
The reaction $2FeCl_3 + SnCl_2 \to 2FeCl_2 + SnCl_4$ is an example of
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View SolutionFor a reaction,$I^{-} + OCl^{-} \to IO^{-} + Cl^{-}$ in an aqueous medium,the rate of reaction is given by $\frac{d[IO^{-}]}{dt} = k[I^{-}][OCl^{-}]$. The overall order of reaction is
Medium
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