Which of the following is a buffer solution?

$pH$ of a mixture of $1 \ M \ HA$ $(pK_a = 4.2)$ and $1 \ M \ NaA$ is $4.5$. In $300 \ mL$ of buffer,the volume of $HA$ is $....... \ mL$ $[\log \ 2 = 0.3]$

The $OH^{-}$ concentration in a mixture of $5.0 \ mL$ of $0.0504 \ M \ NH_{4}Cl$ and $2 \ mL$ of $0.0210 \ M \ NH_{3}$ solution is $x \times 10^{-6} \ M$. The value of $x$ is ..... .
(Nearest integer)
$[ \text{Given } K_{w}=1 \times 10^{-14} \text{ and } K_{b}=1.8 \times 10^{-5} ]$

$A$ solution contains $0.1 \ mol$ of acetic acid and $0.1 \ mol$ of sodium acetate in $500 \ mL$ of solution. If the $pH$ of the solution is $4.74$,find the ionization constant $(K_a)$ of acetic acid.

An acidic buffer is obtained on mixing

$A$ certain buffer solution contains equal concentrations of $X^-$ and $HX$. If the $K_a$ of $HX$ is $10^{-8}$,then the $pH$ of the buffer solution will be ...... .