One mole of $N_2O_4(g)$ is taken in a closed vessel at $300 \, K$ under $1 \, atm$ pressure. When it is heated to $600 \, K$,$20 \%$ of $N_2O_4(g)$ dissociates into $NO_2(g)$. What is the final pressure in $atm$?

$A$ mixture of $SO_2$ and $O_2$ at $5 \, atm$ pressure reacts $30\%$ until equilibrium is reached. Determine the total pressure of the equilibrium mixture in $atm$.
$2SO_{2(g)} + O_{2(g)} \rightleftharpoons 2SO_{3(g)}$

At $T(K)$,the $K_c$ value of the reaction $AO_{2(g)} + BO_{2(g)} \rightleftharpoons AO_{3(g)} + BO_{(g)}$ is $16$. In a closed $1 \ L$ flask,one mole each of $AO_2, BO_2, AO_3$ and $BO$ are taken and heated to $T(K)$. Identify the correct statements about this equilibrium.
$I)$ Total number of moles at equilibrium is $4$
$II)$ At equilibrium,the ratio of moles of $AO_2$ and $AO_3$ is $1:4$
$III)$ Total number of moles of $AO_2$ and $BO_2$ at equilibrium is $0.8$

Which of the following statements is correct?

$\Delta _f G^o$ at $500 \, K$ for substance '$S$' in liquid state and gaseous state are $+100.7 \, kcal \, mol^{-1}$ and $+103 \, kcal \, mol^{-1}$,respectively. The vapour pressure of liquid '$S$' at $500 \, K$ is approximately equal to $(R = 2 \, cal \, K^{-1} \, mol^{-1}) \dots \dots \text{atm}$.

For the gas phase reaction; $C_2H_{4(g)} + H_{2(g)} \rightleftharpoons C_2H_{6(g)}$,$\Delta H = -32.7 \ kcal$ carried out in a vessel,the equilibrium concentration of $C_2H_4$ can be increased by: