At $25^\circ \text{C}$,given the following data: $Ag_{(s)} + I^-_{(aq)} \rightarrow AgI_{(s)} + e^-$,$E^o = 0.152 \ V$; $Ag_{(s)} \rightarrow Ag^+_{(aq)} + e^-$,$E^o = -0.800 \ V$. What is the value of $\log \ K_{sp}$ for $AgI$? (where $K_{sp} = \text{solubility product}$)

Consider the following electrochemical cell at standard condition: $Au_{(s)} | QH_2, Q | NH_4X(0.01 \ M) || Ag^{+}(1 \ M) | Ag_{(s)}$. Given $E_{\text{cell}} = +0.4 \ V$. The couple $QH_2 / Q$ represents the quinhydrone electrode,and the half-cell reaction is given as: $Q + 2e^- + 2H^+ \rightarrow QH_2$ with $E^o_{Q/QH_2} = +0.7 \ V$. Given: $E^o_{Ag^+/Ag} = +0.8 \ V$ and $\frac{2.303 \ RT}{F} = 0.06 \ V$. The $pK_b$ value of the ammonium halide salt $(NH_4X)$ used here is $.........$ (nearest integer).

The standard electrode potential $E^{\ominus}$ and its temperature coefficient $\left( \frac{dE^{\ominus}}{dT} \right)$ for a cell are $2 \ V$ and $-5 \times 10^{-4} \ V \ K^{-1}$ at $300 \ K$ respectively. The cell reaction is
$Zn_{(s)} + Cu^{2+}_{(aq)} \rightleftharpoons Zn^{2+}_{(aq)} + Cu_{(s)}$
Standard reaction enthalpy $\left( \Delta_r H^{\ominus} \right)$ is ....... $kJ$

The value of $E_1^{\circ}$ is (in $V$)

Which of the following statements is wrong?

During the electrolysis of carnallite,$MgCl_2$ is decomposed and not $KCl$. This is because of