The IUPAC name of K_2[OsCl_5N] is: | vedclass

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Question

(C) $1$. Identify the coordination entity: $[OsCl_5N]^{2-}$.$2$. The ligand $N^{3-}$ is named as 'nitrido'.$3$. The ligand $Cl^-$ is named as 'chloro'

Vedclass · Accepted Answer

Potassium pentachloronitridoosmate $(VI)$

Vedclass · Answer

(C) $1$. Identify the coordination entity: $[OsCl_5N]^{2-}$.$2$. The ligand $N^{3-}$ is named as 'nitrido'.$3$. The ligand $Cl^-$ is named as 'chloro'.$4$. The oxidation state of $Os$ is calculated as: $x + 5(-1) + (-3) = -2$,which gives $x - 8 = -2$,so $x = +6$.$5$. Since the complex ion is anionic,the metal name ends in '-ate',so $Os$ becomes 'osmate'.$6$. Combining these,the name is Potassium pentachloronitridoosmate $(VI)$.

The $IUPAC$ name of $K_2[OsCl_5N]$ is:

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