Which of the following statements regarding the chemical properties of acetophenone is incorrect?
$I.$ It is reduced to methyl phenyl carbinol by sodium and ethanol.
$II.$ It is oxidized to benzoic acid with acidic $KMnO_4$.
$III.$ It does not undergo electrophilic substitution reactions (like nitration at the $m$-position).
$IV.$ It does not give the iodoform test with iodine and alkali.

Which of the following is most reactive towards the addition reaction of hydrogen cyanide to form the corresponding cyanohydrin?

An organic compound $(A)$ with molecular formula $C_8H_8O$ forms an orange-red precipitate with $2,4-DNP$ reagent and gives a yellow precipitate on heating with iodine in the presence of sodium hydroxide. It neither reduces Tollens' or Fehlings' reagent,nor does it decolourise bromine water or Baeyer's reagent. On drastic oxidation with chromic acid,it gives a carboxylic acid $(B)$ having molecular formula $C_7H_6O_2$. Identify the compounds $(A)$ and $(B)$ and explain the reactions involved.

Reductive amination of $A$ forms :
$A$ :

In a set of the given reactions,acetic acid yielded a product $C$. Product $C$ would be:
$CH_3COOH + PCl_5 \to A$ $\xrightarrow{C_6H_6, \text{anh. } AlCl_3} B$ $\xrightarrow{C_2H_5MgBr, \text{ether}} C$

Which of the following reagents would carry out the following transformation?
$C_6H_5COCH_3 \rightarrow C_6H_5CH(OD)CH_3$ (Note: The product shows a deuterium atom attached to the chiral carbon,not the oxygen).