$A$ blue colouration is not obtained when:

  • A
    Ammonium hydroxide dissolves in copper sulphate
  • B
    Copper sulphate solution reacts with $K_4[Fe(CN)_6]$
  • C
    Ferric chloride reacts with sodium ferrocyanide
  • D
    Anhydrous $CuSO_4$ is dissolved in water

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The number of ions present in $2.0 \ L$ of a solution of $0.8 \ M \ K_4[Fe(CN)_6]$ is

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The magnetic moment (spin only) of an octahedral complex having $CFSE = -0.8 \Delta_0$ and surrounded by weak field ligands can be:

The reaction of aqueous $[Ni(H_2O)_6]^{2+}$ is performed by the addition of a bidentate ligand ethane-$1,2$-diamine $(en)$. Match the following:
$[Ni(H_2O)_6]^{2+} : en$ molar ratioColour of the product
$A. 1:1$$I. \text{Pale blue}$
$B. 1:2$$II. \text{Blue/Purple}$
$C. 1:3$$III. \text{Violet}$

The correct match is:

List-$I$ contains metal species and List-$II$ contains their properties.
List-$I$ List-$II$
$I$. $[Cr(CN)_6]^{4-}$ $P$. $t_{2g}$ orbitals contain $4$ electrons
$II$. $[RuCl_6]^{2-}$ $Q$. $\mu$ (spin-only) $= 4.9 \ BM$
$III$. $[Cr(H_2O)_6]^{2+}$ $R$. low spin complex ion
$IV$. $[Fe(H_2O)_6]^{2+}$ $S$. metal ion in $4+$ oxidation state
$T$. $d^4$ species

[Given: Atomic number of $Cr = 24, Ru = 44, Fe = 26$] Match each metal species in List-$I$ with their properties in List-$II$,and choose the correct option.

The number of ions present in $2 \ L$ of a solution of $1.6 \ M \ K_4[Fe(CN)_6]$ is:

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