$A$ reaction at $1 \ bar$ is non-spontaneous at low temperature but becomes spontaneous at high temperature. Identify the correct statement about the reaction among the following:

  • A
    $\Delta H$ is positive and $\Delta S$ is positive
  • B
    $\Delta H$ is negative and $\Delta S$ is negative
  • C
    $\Delta H$ is positive and $\Delta S$ is negative
  • D
    $\Delta H$ is negative and $\Delta S$ is positive

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Similar Questions

Compare the following criteria for spontaneity of a reaction based on the values of $\Delta_{\text{r}}H^0$,$\Delta_{\text{r}}S^0$,and $\Delta_{\text{r}}G^0$:
$\Delta_{\text{r}}H^0$$\Delta_{\text{r}}S^0$$\Delta_{\text{r}}G^0$Description
$(a) (+)$$(-)$$(+)$$(i) \text{ Non-spontaneous at all temperatures}$
$(b) (-)$$(-)$$(-)$$(ii) \text{ Spontaneous at low temperatures}$
$(c) (-)$$(+)$$(-)$$(iii) \text{ Spontaneous at all temperatures}$

$A$ chemical reaction cannot occur at all if

Calculate the work done when $1 \text{ mole}$ of an ideal gas is expanded reversibly and isothermally from an initial pressure $P_1 = 10 \text{ bar}$ to a final pressure $P_2 = 1 \text{ bar}$ at a constant temperature $T = 300 \text{ K}$. $[R = 8.314 \text{ J K}^{-1} \text{ mol}^{-1}]$ (in $\text{ kJ}$)

The correct thermodynamic conditions for a spontaneous reaction at all temperatures are:

For a reaction at $25^o C$,$\Delta H > 0$ and $\Delta S > 0$. Under what conditions will this reaction become spontaneous?

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