$A$ vessel contains $14 \, g$ ($7$ moles) of hydrogen and $96 \, g$ ($3$ moles) of oxygen at $STP$. $A$ chemical reaction is induced by passing an electric spark in the vessel until one of the gases is consumed. The temperature is brought back to its starting value of $273 \, K$. The pressure in the vessel is ...... $atm$.

  • A
    $0.1$
  • B
    $0.2$
  • C
    $0.3$
  • D
    $0.4$

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Nitrogen gas is filled in an insulated container. If $\alpha$ fraction of moles dissociates without exchange of any energy,then the fractional change in its temperature is ..............

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$A$ diatomic gas of molecular weight $30 \, g/mol$ is filled in a container at $27 \, ^\circ C$. It is moving at a velocity of $100 \, m/s$. If it is suddenly stopped,the rise in temperature of the gas is:

The figure shows a plot of $PV/T$ versus $P$ for $1.00 \times 10^{-3} \; kg$ of oxygen gas at two different temperatures.
$(a)$ What does the dotted plot signify?
$(b)$ Which is true: $T_{1} > T_{2}$ or $T_{1} < T_{2}$?
$(c)$ What is the value of $PV/T$ where the curves meet on the $y$-axis?
$(d)$ If we obtained similar plots for $1.00 \times 10^{-3} \; kg$ of hydrogen,would we get the same value of $PV/T$ at the point where the curves meet on the $y$-axis? If not,what mass of hydrogen yields the same value of $PV/T$ (for the low-pressure,high-temperature region of the plot)?
(Molecular mass of $H_{2} = 2.02 \; u$,of $O_{2} = 32.0 \; u$,$R = 8.31 \; J \; mol^{-1} K^{-1}$.)

$A$ horizontal uniform glass tube of $100 \ cm$ length, sealed at both ends, contains a $10 \ cm$ mercury column in the middle. The temperature and pressure of air on either side of the mercury column are $31^{\circ} C$ and $76 \ cm$ of mercury, respectively. If the air column at one end is kept at $0^{\circ} C$ and the other end at $273^{\circ} C$, then the pressure of air which is at $0^{\circ} C$ is (in $cm$ of $Hg$):

Two rigid boxes containing different ideal gases are placed on a table. Box $A$ contains one mole of nitrogen at temperature $T_0$,while Box $B$ contains one mole of helium at temperature $(7/3)T_0$. The boxes are then put into thermal contact with each other,and heat flows between them until the gases reach a common final temperature (ignore the heat capacity of the boxes). The final temperature of the gases,$T_f$,in terms of $T_0$ is:

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