According to Valence Bond Theory,the number of unpaired electrons present in $[MnCl_6]^{3-}$,$[Fe(CN)_6]^{3-}$ and $[Co(C_2O_4)_3]^{3-}$,respectively,are

  • A
    $0; 5; 0$
  • B
    $4; 3; 2$
  • C
    $4; 1; 0$
  • D
    $5; 4; 3$

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The number of species from the following that are involved in $sp^3 d^2$ hybridization is $[Co(NH_3)_6]^{3+}, SF_6, [CrF_6]^{3-}, [CoF_6]^{3-}, [Mn(CN)_6]^{3-}$ and $[MnCl_6]^{3-}$.

The shape of the manganate ion $(MnO_4^{2-})$ is . . . . . . .

For octahedral $Mn(II)$ and tetrahedral $Ni(II)$ complexes,consider the following statements:
$(I)$ Both the complexes can be high spin.
$(II)$ $Ni(II)$ complex can very rarely be low spin.
$(III)$ With strong field ligands,$Mn(II)$ complexes can be low spin.
$(IV)$ Aqueous solution of $Mn(II)$ ions is yellow in color.

Nickel $(Z = 28)$ forms a paramagnetic complex $[NiX_4]^{2-}$ with a uninegative monodentate ligand $X^-$. The number of unpaired electrons in nickel and the geometry of this complex ion are,respectively:

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$[Co(NH_3)_6]^{3+}$ and $[CoF_6]^{3-}$ are respectively known as:

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