According to Werner’s theory,the geometry of the complex is determined by:

  • A
    Only from the primary valence in space
  • B
    Number and position of the primary valences in space
  • C
    Number and position of the secondary valences in space
  • D
    Only from the position of secondary valence in space

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$K_3[CoF_6]$ is a high-spin complex. The hybridization state of $Co$ in this complex is .....................

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Briefly explain the Valence Bond Theory $(VBT)$.

The number of unpaired electrons responsible for the paramagnetic nature of the following complex species are respectively $:$
$[Fe(CN)_6]^{3-}, [FeF_6]^{3-}, [CoF_6]^{3-}, [Mn(CN)_6]^{3-}$

Match List-$I$ (Species) with List-$II$ (Hybrid orbitals used by the central atom in their formation) and select the correct answer.
List-$I$ List-$II$
$A. \, Ni(CN)_5^{3-}$ $1. \, sp^3$
$B. \, CuCl_5^{3-}$ $2. \, dsp^2$
$C. \, AuCl_4^-$ $3. \, sp^3d_{z^2}$
$D. \, ClO_4^-$ $4. \, d_{x^2-y^2}sp^3$

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Which statement is correct?

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