Air containing $79\%$ of nitrogen and $21\%$ of oxygen by volume is heated at $2200 \ K$ and $1 \ atm$ until equilibrium is established according to the reaction $N_{2(g)} + O_{2(g)} \rightleftharpoons 2NO_{(g)}$. If the $K_p$ of the reaction is $1.1 \times 10^{-3}$,calculate the amount of nitric oxide produced in terms of volume percent.

$A$ reaction mixture containing $H_2, N_2$ and $NH_3$ has partial pressures of $2 \ atm, 1 \ atm$ and $3 \ atm$ respectively at $725 \ K.$ If the value of $K_P$ for the reaction,$N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)$ is $4.28 \times 10^{-5} \ atm^{-2}$ at $725 \ K,$ in which direction will the net reaction proceed?

$CH_3COOH_{(l)} + C_2H_5OH_{(l)} \rightleftharpoons CH_3COOC_2H_{5_{(l)}} + H_2O_{(l)}$. In the above reaction,one mole of each of acetic acid and alcohol are heated in the presence of a little conc. $H_2SO_4$. On equilibrium being attained:

The reaction $2H_2S_{(g)} \rightleftharpoons 2H_{2_{(g)}} + S_{2_{(g)}}$ is in equilibrium. If $0.5 \ mol$ of $H_2S$,$0.10 \ mol$ of $H_2$,and $0.4 \ mol$ of $S_2$ are taken in a $1 \ L$ vessel,the value of the equilibrium constant $(K)$ is .... $mol \ L^{-1}$.

The equilibrium constants $K_{p1}$ and $K_{p2}$ for the reactions $X \rightleftharpoons 2Y$ and $Z \rightleftharpoons P + Q$ respectively are in the ratio of $1 : 9$. If the degree of dissociation of $X$ and $Z$ be equal,then the ratio of total pressures at these equilibria is:

At $473 \ K$, equilibrium constant $K_{c}$ for decomposition of phosphorus pentachloride, $PCl_{5}$, is $8.3 \times 10^{-3}$. If decomposition is depicted as,
$PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)}, \Delta_{r}H^{\Theta} = 124.0 \ kJ \ mol^{-1}$
$(a)$ Write an expression for $K_{c}$ for the reaction.
$(b)$ What is the value of $K_{c}$ for the reverse reaction at the same temperature?
$(c)$ What would be the effect on $K_{c}$ if $(i)$ more $PCl_{5}$ is added $(ii)$ pressure is increased $(iii)$ the temperature is increased?