An equilibrium shifts towards reactants at higher temperatures. Find the correct graph.

The equilibrium constants $K_{p_1}$ and $K_{p_2}$ for the reactions $X \rightleftharpoons 2Y$ and $Z \rightleftharpoons P + Q$ are in the ratio of $1 : 4$. If the degree of dissociation of $X$ is $2$ times that of $Z$,then the ratio of total pressure $(P_1 : P_2)$ at these equilibria is: (Assume degree of dissociation for both reactions are very small)

Air containing $79\%$ of nitrogen and $21\%$ of oxygen by volume is heated at $2200 \ K$ and $1 \ atm$ until equilibrium is established according to the reaction $N_{2(g)} + O_{2(g)} \rightleftharpoons 2NO_{(g)}$. If the $K_p$ of the reaction is $1.1 \times 10^{-3}$,calculate the amount of nitric oxide produced in terms of volume percent.

Match the items in List-$X$ with List-$Y$ and select the correct option.

List-$X$	List-$Y$
$(A)$ $A_{(g)} \rightleftharpoons B_{(g)} + \text{Heat}$	$(i)$ Equilibrium constant
$(B)$ $r_b/r_f$	$(ii)$ Favored at low temperature
$(C)$ $r_f/r_b$	$(iii)$ [Equilibrium constant]$^{-1}$
$(D)$ $2A_{(g)} + B_{(g)} \rightleftharpoons C_{(g)}$	$(iv)$ $A_{(g)} + B_{(g)} \rightleftharpoons C_{(g)} + D_{(g)}$
$(E)$ Effect of pressure	$(V)$ $\Delta n < 0$

The following reaction is performed at $298 \, K$.
$2 NO_{(g)} + O_{2(g)} \rightleftharpoons 2 NO_{2(g)}$
The standard free energy of formation of $NO_{(g)}$ is $86.6 \, kJ/mol$ at $298 \, K$. What is the standard free energy of formation of $NO_{2(g)}$ at $298 \, K$? $(K_p = 1.6 \times 10^{12})$

When $2 \ L$ of $CO_2$ is heated with graphite,the volume of gases collected is $3 \ L$. Calculate the number of moles of $CO$ produced at $STP$.