An ideal gas is expanded from $(p_1, V_1, T_1)$ to $(p_2, V_2, T_2)$ under different conditions. The correct statement$(s)$ among the following is(are):
[$A$] The work done on the gas is maximum when it is compressed irreversibly from $(p_2, V_2)$ to $(p_1, V_1)$ against constant pressure $p_1$.
[$B$] The work done by the gas is less when it is expanded reversibly from $V_1$ to $V_2$ under adiabatic conditions as compared to that when expanded reversibly from $V_1$ to $V_2$ under isothermal conditions.
[$C$] The change in internal energy of the gas is $(i)$ zero,if it is expanded reversibly with $T_1=T_2$,and $(ii)$ positive,if it is expanded reversibly under adiabatic conditions with $T_1 \neq T_2$.
[$D$] If the expansion is carried out freely,it is simultaneously both isothermal as well as adiabatic.
[$A$] The work done on the gas is maximum when it is compressed irreversibly from $(p_2, V_2)$ to $(p_1, V_1)$ against constant pressure $p_1$.
[$B$] The work done by the gas is less when it is expanded reversibly from $V_1$ to $V_2$ under adiabatic conditions as compared to that when expanded reversibly from $V_1$ to $V_2$ under isothermal conditions.
[$C$] The change in internal energy of the gas is $(i)$ zero,if it is expanded reversibly with $T_1=T_2$,and $(ii)$ positive,if it is expanded reversibly under adiabatic conditions with $T_1 \neq T_2$.
[$D$] If the expansion is carried out freely,it is simultaneously both isothermal as well as adiabatic.
- A$A, B, C$
- B$A, B, D$
- C$A, B$
- D$A, D$
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Similar Questions
If $100$ mole of $H_2O_2$ decomposes at $1$ bar and $300$ $K$,the work done $(kJ)$ by $50$ mole of $O_{2(g)}$ as it expands against $1$ bar pressure is............. $kJ$
$2H_2O_{2(l)} \rightleftharpoons 2H_2O_{(l)} + O_{2(g)}$
$(R = 8.3 \ J \ K^{-1} \ mol^{-1})$
$2H_2O_{2(l)} \rightleftharpoons 2H_2O_{(l)} + O_{2(g)}$
$(R = 8.3 \ J \ K^{-1} \ mol^{-1})$
DifficultJEE MAIN 2016
View SolutionFor the reaction $2A_{(g)} + B_{(g)} \to 2D_{(g)}$,given $\Delta U^{\theta} = -10.5 \ kJ$ and $\Delta S^{\theta} = -44.1 \ J \ K^{-1}$. Calculate $\Delta G^{\theta}$ for the reaction at $298 \ K$ and predict whether the reaction may occur spontaneously.
Medium
View SolutionThe free energy change for the following reactions are given below:
$C_2H_{2(g)} + \frac{5}{2}O_{2(g)} \to 2CO_{2(g)} + H_2O_{(l)}; \Delta G^o = -1234 \ kJ$
$C_{(s)} + O_{2(g)} \to CO_{2(g)}; \Delta G^o = -394 \ kJ$
$H_{2(g)} + \frac{1}{2}O_{2(g)} \to H_2O_{(l)}; \Delta G^o = -237 \ kJ$
What is the standard free energy change for the reaction $H_{2(g)} + 2C_{(s)} \to C_2H_{2(g)}$ in $kJ$?
$C_2H_{2(g)} + \frac{5}{2}O_{2(g)} \to 2CO_{2(g)} + H_2O_{(l)}; \Delta G^o = -1234 \ kJ$
$C_{(s)} + O_{2(g)} \to CO_{2(g)}; \Delta G^o = -394 \ kJ$
$H_{2(g)} + \frac{1}{2}O_{2(g)} \to H_2O_{(l)}; \Delta G^o = -237 \ kJ$
What is the standard free energy change for the reaction $H_{2(g)} + 2C_{(s)} \to C_2H_{2(g)}$ in $kJ$?
Medium
View SolutionMatch the following:
List-$I$ List-$II$ $(A) \Delta U = W_{ad}$ $I.$ Isothermal reversible expansion $(B) \Delta U = q - W$ $II.$ Wall is adiabatic $(C) \Delta U = -q$ $III.$ Thermally conducting walls $(D) \Delta U = 0$ $IV.$ Isolated system $V.$ Closed system
The correct answer is
| List-$I$ | List-$II$ |
|---|---|
| $(A) \Delta U = W_{ad}$ | $I.$ Isothermal reversible expansion |
| $(B) \Delta U = q - W$ | $II.$ Wall is adiabatic |
| $(C) \Delta U = -q$ | $III.$ Thermally conducting walls |
| $(D) \Delta U = 0$ | $IV.$ Isolated system |
| $V.$ Closed system |
The correct answer is
Chloroform has $\Delta H_{vaporization} = 29.2 \ kJ/mol$ and boils at $61.2 \ ^oC$. What is the value of $\Delta S_{vaporization}$ for chloroform? $...... \ J/mol \ K$
Medium
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