An ideal gas is in thermodynamic equilibrium. The number of degrees of freedom of a molecule of the gas is $n$. The internal energy of one mole of the gas is $U_n$ and the speed of sound in the gas is $v_n$. At a fixed temperature and pressure,which of the following is the correct option?

$4.0 \, g$ of a gas occupies $22.4 \, L$ at $NTP$. The specific heat capacity of the gas at constant volume is $5.0 \, J K^{-1} mol^{-1}$. If the speed of sound in this gas at $NTP$ is $952 \, m s^{-1}$,then the heat capacity at constant pressure is .... $J K^{-1} mol^{-1}$ (Take gas constant $R = 8.3 \, J K^{-1} mol^{-1}$)

An ideal gas filled in a cylinder occupies volume $V$. The gas is compressed isothermally to the volume $V/3$. Now,the cylinder valve is opened and the gas is allowed to leak keeping temperature same. What percentage of the number of molecules should escape to bring the pressure in the cylinder back to its original value (in $\%$)?

Given below are two statements:
Statement $I$: The temperature of a gas is $-73^{\circ} C$. When the gas is heated to $527^{\circ} C$,the root mean square speed of the molecules is doubled.
Statement $II$: The product of pressure and volume of an ideal gas is equal to the translational kinetic energy of the molecules.
In the light of the above statements,choose the correct answer from the options given below:

The average translational kinetic energy and the $r.m.s.$ speed of molecules in a sample of oxygen gas at $300 \, K$ are $6.21 \times 10^{-21} \, J$ and $484 \, m/s$ respectively. The corresponding values at $600 \, K$ are nearly (assuming ideal gas behaviour):

Match Column $- I$ and Column $- II$ and choose the correct match from the given choices.

Column $- I$	Column $- II$
$(A)$ Root mean square speed of gas molecules	$(P)$ $\frac{1}{3} n m \bar{v}^{2}$
$(B)$ Pressure exerted by ideal gas	$(Q)$ $\sqrt{\frac{3 RT}{M}}$
$(C)$ Average kinetic energy of a molecule	$(R)$ $\frac{5}{2} RT$
$(D)$ Total internal energy of $1$ mole of a diatomic gas	$(S)$ $\frac{3}{2} k_{B} T$