An organic compound $A$ contains nitrogen and chlorine. It dissolves readily in water to give a solution that turns litmus red. Titration of compound $A$ with standard base indicates that the molecular weight of $A$ is $131 \pm 2$. When a sample of $A$ is treated with aqueous $NaOH$,a liquid separates which contains $N$ but not $Cl$. Treatment of the obtained liquid with nitrous acid followed by phenol gives an orange precipitate. The compound $A$ is:

  • A
    $C_6H_5NH_3Cl$
  • B
    $C_6H_5CH_2NH_2 \cdot HCl$
  • C
    $o-Cl-C_6H_4NH_2$
  • D
    $p-Cl-C_6H_4NH_3Cl$

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Consider the following sequence of reactions:
Chlorobenzene $\xrightarrow[ii) CO_2, H_3O^{+}]{i) Mg, \text{dry ether}} \text{Benzoic acid}$ $\xrightarrow{NH_3, \Delta} \text{Benzamide (A)}$ $\xrightarrow{Br_2, NaOH} \text{Aniline (B)}$
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