Assertion $(A)$: If heat of combustion of $C_2H_6$ is $X \ kJ \ mol^{-1}$,heat liberated on combustion of $150 \ g$ of $C_2H_6$ is $5X \ kJ$.
Reason $(R)$: Enthalpy is an extensive property.

  • A
    Both $(A)$ and $(R)$ are correct,and $(R)$ is the correct explanation of $(A)$
  • B
    Both $(A)$ and $(R)$ are correct,but $(R)$ is not the correct explanation of $(A)$
  • C
    $(A)$ is correct,$(R)$ is not correct
  • D
    $(A)$ is not correct but $(R)$ is correct

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$I$. $\Delta_{r} G$ is zero for $A \rightleftharpoons B$ reaction.
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Observe the following reactions:
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For the complete combustion of ethanol,$C_2H_5OH_{(l)} + 3O_{2(g)} \rightarrow 2CO_{2(g)} + 3H_2O_{(l)}$,the amount of heat produced as measured in a bomb calorimeter is $1364.47 \ kJ \ mol^{-1}$ at $25 \ ^oC$. Assuming ideality,the enthalpy of combustion,$\Delta_cH$,for the reaction will be: $(R = 8.314 \ J \ K^{-1} \ mol^{-1})$ .....$kJ \ mol^{-1}$

Calculate the standard internal energy change for $OF_{2(g)} + H_2O_{(g)} \longrightarrow 2 HF_{(g)} + O_{2(g)}$ at $300 \ K$,if $\Delta_{f} H^{\circ}$ of $OF_{2(g)}$,$H_2O_{(g)}$,and $HF_{(g)}$ are $20$,$-250$,and $-270 \ kJ \ mol^{-1}$ respectively. $[R = 8.314 \ J \ K^{-1} \ mol^{-1}]$ (in $kJ$)

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