For the complete combustion of ethanol,$C_2H_5OH_{(l)} + 3O_{2(g)} \rightarrow 2CO_{2(g)} + 3H_2O_{(l)}$,the amount of heat produced as measured in a bomb calorimeter is $1364.47 \ kJ \ mol^{-1}$ at $25 \ ^oC$. Assuming ideality,the enthalpy of combustion,$\Delta_cH$,for the reaction will be: $(R = 8.314 \ J \ K^{-1} \ mol^{-1})$ .....$kJ \ mol^{-1}$

  • A
    $-1366.95$
  • B
    $-1361.95$
  • C
    $-1460.95$
  • D
    $-1350.50$

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Reversible expansion of an ideal gas under isothermal and adiabatic conditions are as shown in the figure.
$AB \to$ Isothermal expansion
$AC \to$ Adiabatic expansion
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$X \, g$ of ethanol $(CH_3CHO)$ is burnt in a bomb calorimeter and $Y \, J$ of heat is produced. Then,which of the following is correct for the enthalpy of combustion?

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Identify the correct statement from the following regarding a chemical reaction.

$2 \ mol$ of $Hg_{(g)}$ is combusted in a fixed volume bomb calorimeter with excess of $O_2$ at $298 \ K$ and $1 \ atm$ into $HgO_{(s)}$. During the reaction,temperature increases from $298.0 \ K$ to $312.8 \ K$. If heat capacity of the bomb calorimeter and enthalpy of formation of $Hg_{(g)}$ are $20.00 \ kJ \ K^{-1}$ and $61.32 \ kJ \ mol^{-1}$ at $298 \ K$,respectively,the calculated standard molar enthalpy of formation of $HgO_{(s)}$ at $298 \ K$ is $X \ kJ \ mol^{-1}$. The value of $|X|$ is. . . . . [Given : Gas constant $R = 8.3 \ J \ K^{-1} \ mol^{-1}$]

Calculate the standard internal energy change for $OF_{2(g)} + H_2O_{(g)} \longrightarrow 2 HF_{(g)} + O_{2(g)}$ at $300 \ K$,if $\Delta_{f} H^{\circ}$ of $OF_{2(g)}$,$H_2O_{(g)}$,and $HF_{(g)}$ are $20$,$-250$,and $-270 \ kJ \ mol^{-1}$ respectively. $[R = 8.314 \ J \ K^{-1} \ mol^{-1}]$ (in $kJ$)

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