At $25\,^{\circ}C$,the values of rate constant,activation energy and Arrhenius constant of a reaction are $3 \times 10^{-4}\, s^{-1}$,$129\, kJ/mol$ and $2 \times 10^{15}\, s^{-1}$ respectively. The value of rate constant as $T \to \infty$ is

  • A
    zero
  • B
    $2 \times 10^{15}$
  • C
    $3 \times 10^{-4}$
  • D
    $6 \times 10^{11}$

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For a first order reaction,the rate of reaction is $2.4 \times 10^{-3} \ mol \ L^{-1} \ s^{-1}$ at $27 \ ^\circ C$. The activation energy of the reaction is $24.942 \ kJ \ mol^{-1}$. The rate of reaction at $327 \ ^\circ C$ is ....... $mol \ L^{-1} \ s^{-1}$ [Take $e^5 = 150$,$e^{0.005} = 1$,$e^4 = 55$].

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