At $298 \ K$,for the reaction $N_2O_{4(g)} \rightleftharpoons 2NO_{2(g)}$,the $K_p$ value is $0.98$. Predict whether the reaction is spontaneous or not.

  • A
    Spontaneous
  • B
    Non-spontaneous
  • C
    Equilibrium
  • D
    Cannot be determined

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In a closed flask at $600 \text{ K}$, one mole of $X_2Y_4(g)$ attains equilibrium as given below: $X_2Y_4(g) \rightleftharpoons 2XY_2(g)$. At equilibrium, $75\%$ of $X_2Y_4(g)$ is dissociated and the total pressure is $1 \text{ atm}$. The magnitude of $\Delta_r G^\circ$ (in $\text{kJ mol}^{-1}$) at this temperature is . . . . . . .

$STATEMENT-1$: For every chemical reaction at equilibrium,standard Gibbs energy of reaction is zero. $STATEMENT-2$: At constant temperature and pressure,chemical reactions are spontaneous in the direction of decreasing Gibbs energy.

At $320 \ K,$ a gas $A_2$ is $20 \%$ dissociated to $A_{(g)}.$ The standard free energy change at $320 \ K$ and $1 \ atm$ in $J \ mol^{-1}$ is approximately $(R = 8.314 \ J \ K^{-1} \ mol^{-1}; \ \ln \ 2 = 0.693; \ \ln \ 3 = 1.098).$

The $\Delta G^o$ for the reaction $X + Y \rightleftharpoons Z$ is $-4.606 \ kcal$. The value of the equilibrium constant of the reaction at $227 \ ^oC$ is $(R = 2.0 \ cal \ mol^{-1} K^{-1})$.

For the reaction taking place at a certain temperature $NH_2COONH_{4(s)} \rightleftharpoons 2NH_{3(g)} + CO_{2(g)}$,if the equilibrium pressure is $X \ bar$,then $\Delta_r G^o$ would be :-

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