At $T \ K$,$K_{c}$ for the reaction $SO_{2(g)} + NO_{2(g)} \rightleftharpoons SO_{3(g)} + NO_{(g)}$ is $16$. If initially one mole each of all the four gases are taken in a $1 \ L$ vessel,the equilibrium concentrations of $SO_{3(g)}$ and $SO_{2(g)}$ in $mol \ L^{-1}$ respectively are:

Calculate the partial pressure of carbon monoxide from the following data:
$CaCO_{3(s)} \rightleftharpoons CaO_{(s)} + CO_{2(g)}, K_p = 8 \times 10^{-2}$
$CO_{2(g)} + C_{(s)} \rightleftharpoons 2CO_{(g)}, K_p = 2$

At $600 \ K$,$2 \ mol$ of $NO$ are mixed with $1 \ mol$ of $O_2$.
$2 \ NO_{(g)} + O_{2(g)} \rightleftarrows 2 \ NO_{2(g)}$
The reaction occurring as above comes to equilibrium under a total pressure of $1 \ atm$. Analysis of the system shows that $0.6 \ mol$ of oxygen are present at equilibrium. The equilibrium constant for the reaction is $.........$ (Nearest integer).

For the reaction $C_{(s)} + CO_{2(g)} \rightleftharpoons 2CO_{(g)}$,if $25\%$ of $CO_2$ is converted to $CO$ at equilibrium and the total equilibrium pressure is $12 \ atm$,then the partial pressure of $CO_2$ at equilibrium will be............$atm$.

Write a relation between $\Delta G$ and $Q$ and define the meaning of each term and answer the following:
$(a)$ Why a reaction proceeds forward when $Q < K$ and no net reaction occurs when $Q = K$.
$(b)$ Explain the effect of increase in pressure in terms of reaction quotient $Q$.
For the reaction: $CO_{(g)} + 3H_{2(g)} \rightleftharpoons CH_{4(g)} + H_{2}O_{(g)}$

For the reaction $2SO_3 \rightleftharpoons 2SO_2 + O_2$,if $K_c = 100$ and the degree of dissociation $\alpha = 1$,determine the concentration of $O_2$ when the concentration of $SO_3$ is equal to the concentration of $SO_2$.