At $25^{\circ} \text{C}$, the standard enthalpies of combustion of $H_2(g)$, cyclohexene $(C_6H_{10})$, and cyclohexane $(C_6H_{12})$ are $-241 \text{ kJ mol}^{-1}$, $-3800 \text{ kJ mol}^{-1}$, and $-3920 \text{ kJ mol}^{-1}$ respectively. Calculate the heat of hydrogenation of cyclohexene.

  • A
    $-121 \text{ kJ mol}^{-1}$
  • B
    $-242 \text{ kJ mol}^{-1}$
  • C
    $121 \text{ kJ mol}^{-1}$
  • D
    $363 \text{ kJ mol}^{-1}$

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Based on Hess's law calculations,what is the average bond energy of $S-O$ in $SO_3$ if $\Delta H_f^o$ of $SO_3$ is $-270 \ kJ \ mol^{-1}$. The bond energy of $O=O$ is $495 \ kJ \ mol^{-1}$ and the heat of sublimation for $S_{(s)}$ is $277 \ kJ \ mol^{-1}$? (Given: Bond energy of $S=O$ is not provided,assume the reaction $S_{(s)} + \frac{3}{2} O_2(g) \rightarrow SO_3(g)$). Note: The provided values in the prompt were inconsistent with standard chemical data; using standard values: $\Delta H_{sub}(S) = 277 \ kJ \ mol^{-1}$,$BE(O=O) = 495 \ kJ \ mol^{-1}$,$BE(S-O) = 330 \ kJ \ mol^{-1}$ is not the goal,we calculate based on the provided logic.

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The heat of hydrogenation of cyclohexene is $28.6 \, kcal$ and that of cyclohexadiene is slightly more than double,$(55.4 \, kcal)$. What will be the heat of hydrogenation of benzene,which contains three double bonds?

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Calculate the heat of combustion (in $kJ$) of methane from the following data:
$(i)$ $C_{\text{(graphite)}} + 2H_{2(g)} \rightarrow CH_{4(g)} \quad \Delta H = -74.8 \ kJ$
(ii) $C_{\text{(graphite)}} + O_{2(g)} \rightarrow CO_{2(g)} \quad \Delta H = -393.5 \ kJ$
(iii) $H_{2(g)} + 1/2 O_{2(g)} \rightarrow H_2O_{(l)} \quad \Delta H = -286.2 \ kJ$

The enthalpy of neutralization of any strong acid and strong base is constant because......

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