Based on the first law of thermodynamics,which one of the following is correct?

An ideal gas,$\overline{C}_{V} = \frac{5}{2} R$,is expanded adiabatically against a constant pressure of $1 \ atm$ until it doubles in volume. If the initial temperature and pressure are $298 \ K$ and $5 \ atm$,respectively,then the final temperature is . . . . . . $K$ (nearest integer). [$\overline{C}_{V}$ is the molar heat capacity at constant volume]

Assertion : For an isothermal reversible process $Q = -W$,i.e.,work done by the system equals the heat absorbed by the system.
Reason : Enthalpy change $(\Delta H)$ is zero for an isothermal process.

If $1.5 \ L$ of an ideal gas at a pressure of $20 \ atm$ expands isothermally and reversibly to a final volume of $15 \ L$,the work done by the gas in $L \ atm$ is

For the combustion of sucrose $(C_{12}H_{22}O_{11})$ at $250\,^oC$,which of the following is true?

$A$ gas is allowed to expand in a well-insulated container against a constant external pressure of $2.5 \ atm$ from an initial volume of $2.50 \ L$ to a final volume of $4.50 \ L$. The change in internal energy $\Delta U$ of the gas in joules will be .............. $J$.