Benzoic acid undergoes dimerisation in benzene solution. The van't Hoff factor $(i)$ is related to the degree of association '$x$' of the acid as

For a $0.1 \ M$ $Ba(NO_3)_2$ solution,the van't Hoff factor is $2.74$. The degree of dissociation is ....... $\%$.

Molecules of benzoic acid $(C_6H_5COOH)$ dimerise in benzene. '$w$' $g$ of the acid dissolved in $30 \ g$ of benzene shows a depression in freezing point equal to $2 \ K.$ If the percentage association of the acid to form dimer in the solution is $80,$ then $w$ is : ............. $g$
(Given that $K_f = 5 \ K \ kg \ mol^{-1},$ Molar mass of benzoic acid $= 122 \ g \ mol^{-1}$ )

When $20 \ g$ of naphthoic acid $(C_{11}H_8O_2)$ is dissolved in $50 \ g$ of benzene, a freezing point depression of $2 \ K$ is observed. The van't Hoff factor $(i)$ is [$K_f = 1.72 \ K \ kg \ mol^{-1}$].

The measured freezing point depression for a $0.1 \ m$ aqueous $CH_{3}COOH$ solution is $0.19^{\circ} C$. The acid dissociation constant $K_{a}$ at this concentration will be (Given, $K_{f}$ the molal cryoscopic constant $= 1.86 \ K \ kg \ mol^{-1}$)

One molal solution of a carboxylic acid in benzene shows the elevation of boiling point of $1.518 \ K$. The degree of association for dimerization of the acid in benzene is $........ \%$. ($K_b$ for benzene $= 2.53 \ K \ kg \ mol^{-1}$)