Buffer solutions have constant acidity and alkalinity because

  • A
    these give unionised acid or base on reaction with added acid or alkali
  • B
    acids and alkalies in these solutions are shielded from attack by other ions
  • C
    they have large excess of $H^{+}$ or $OH^{-}$ ions
  • D
    they have fixed value of $pH$.

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The $K_a$ of $CH_3COOH$ is $1.8 \times 10^{-5}$. How many grams of $CH_3COONa$ are required in $0.1 \ M \ CH_3COOH$ to form a solution having $pH = 4.0$? (Molecular mass of $CH_3COONa = 82 \ g \ mol^{-1}$)

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$A$ buffer solution is prepared by mixing $0.2 \ M$ sodium acetate and $0.1 \ M$ acetic acid. If $pK_{a}$ for acetic acid is $4.7$,find the $pH$.

In a mixture of acetic acid and sodium acetate,the ratio of the concentration of the salt to the acid is increased ten times. Then the $pH$ of the solution:

Assertion $(A)$: The $pH$ of a buffer solution containing equal moles of acetic acid and sodium acetate is $4.8$ ($pK_a$ of acetic acid is $4.8$).
Reason $(R)$: The ionic product of water at $25^{\circ} C$ is $10^{-14} \ mol^2 \ L^{-2}$. The correct answer is

Which of the following mixtures forms an acidic buffer?

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