Calculate $\Delta G^\circ$ for the conversion of oxygen to ozone $\frac{3}{2} O_{2(g)} \to O_{3(g)}$ at $298 \ K$,if $K_p$ for this conversion is $2.47 \times 10^{-29}$.

  • A
    $163 \ kJ \ mol^{-1}$
  • B
    $2.4 \times 10^2 \ kJ \ mol^{-1}$
  • C
    $1.63 \ kJ \ mol^{-1}$
  • D
    $2.38 \times 10^6 \ kJ \ mol^{-1}$

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The reaction,$CaCO_{3(s)} \rightleftharpoons CaO_{(s)} + CO_{2(g)}$ is in equilibrium in a closed vessel at $298 \, K$. The partial pressure (in $atm$) of $CO_{2(g)}$ in the reaction vessel is closest to $....$ [Given : The change in Gibbs energies of formation at $298 \, K$ and $1 \, bar$ for $CaO_{(s)} = -603.501 \, kJ \, mol^{-1}$,$CO_{2(g)} = -394.389 \, kJ \, mol^{-1}$,$CaCO_{3(s)} = -1128.79 \, kJ \, mol^{-1}$,Gas constant,$R = 8.314 \, J \, K^{-1} \, mol^{-1}$]

Find out $\ln K_{eq}$ for the formation of $NO_2$ from $NO$ and $O_2$ at $298 \ K$.
$NO_{(g)} + \frac{1}{2} O_{2(g)} \rightleftharpoons NO_{2(g)}$
Given:
$\Delta G^o_f (NO_2) = 52.0 \ kJ/mol$
$\Delta G^o_f (NO) = 87.0 \ kJ/mol$
$\Delta G^o_f (O_2) = 0 \ kJ/mol$

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Consider the reaction $A \rightleftharpoons B$ at $1000 \ K$. At time $t^{\prime}$,the temperature of the system was increased to $2000 \ K$ and the system was allowed to reach equilibrium. Throughout this experiment,the partial pressure of $A$ was maintained at $1 \ bar$. Given below is the plot of the partial pressure of $B$ with time. What is the ratio of the standard Gibbs energy of the reaction at $1000 \ K$ to that at $2000 \ K$?

Calculate $\Delta G^\circ$ for the reaction, $CH_4(g) + H_2(g) \rightarrow C_2H_6(g)$ at $298 \text{ K}$, given $K_p = 2 \times 10^{17}$ and $R = 8.314 \text{ J K}^{-1} \text{mol}^{-1}$.

Which of the following correctly represents the relationship between $\Delta G$ and $\Delta G^{\circ}$? $[P = \text{products}, R = \text{reactants}]$

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