Calculate the standard free energy change for the reaction $\frac{1}{2}Cu_{(s)} + \frac{1}{2}Cl_{2(g)} \rightleftharpoons \frac{1}{2}Cu^{2+} + Cl^-$ taking place at $25\ ^oC$ in a cell whose standard e.m.f. is $1.02 \ V$ (in $J$).

  • A
    $-98430$
  • B
    $98430$
  • C
    $96500$
  • D
    $-49215$

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For the following cell reaction,$Ag | Ag^{+} | AgCl | Cl^{-} | Cl_2, Pt$
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The $E^o$ values of $Mg^{2+}/Mg$ is $-2.37 \ V$,$Zn^{2+}/Zn$ is $-0.76 \ V$,and $Fe^{2+}/Fe$ is $-0.44 \ V$. Which of the following statements is correct?

$E^o_{cell}$ for the cell: $Pt_{(s)} | H_{2(g)} | HCOOH_{(aq)} || CH_3COOH_{(aq)} | H_{2(g)} | Pt_{(s)}$ at $25^oC$ is ............ $V$. ($K_a$ of $HCOOH = 2.4 \times 10^{-4}$,$K_a$ of $CH_3COOH = 1.8 \times 10^{-5}$,$\log 2 = 0.3$,$\log 3 = 0.477$,$\frac{2.303RT}{F} = 0.059$ or $0.06$)

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Which statement is correct for $\Delta G$ and $E_{cell}$ for a cell reaction?

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