Consider a $70 \%$ efficient hydrogen-oxygen fuel cell working under standard conditions at $1 \ bar$ and $298 \ K$. Its cell reaction is
$H_{2(g)} + \frac{1}{2} O_{2(g)} \rightarrow H_2O(\ell)$
The work derived from the cell on the consumption of $1.0 \times 10^{-3} \ mol$ of $H_{2(g)}$ is used to compress $1.00 \ mol$ of a monoatomic ideal gas in a thermally insulated container. What is the change in the temperature (in $K$) of the ideal gas?
The standard reduction potentials for the two half-cells are given below.
$O_{2(g)} + 4H^{+}(aq.) + 4e^- \rightarrow 2H_2O(\ell), E^{\circ} = 1.23 \ V$
$2H^{+}(aq.) + 2e^- \rightarrow H_{2(g)}, E^{\circ} = 0.00 \ V$
Use $F = 96500 \ C \ mol^{-1}, R = 8.314 \ J \ mol^{-1} \ K^{-1}$

  • A
    $13.32$
  • B
    $13.35$
  • C
    $13.40$
  • D
    $13.45$

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Match List-$I$ with List-$II$.
List-$I$ (Conversion) List-$II$ (Number of Faraday required)
$A$. $1 \ mol$ of $H_2O$ to $O_2$ $I$. $3 \ F$
$B$. $1 \ mol$ of $MnO_4^{-}$ to $Mn^{2+}$ $II$. $2 \ F$
$C$. $1.5 \ mol$ of $Ca$ from molten $CaCl_2$ $III$. $1 \ F$
$D$. $1 \ mol$ of $FeO$ to $Fe_2O_3$ $IV$. $5 \ F$

Choose the correct answer from the options given below:

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