Consider the cell reaction at $300 \ K$: $A_{(s)} + B^{2+}_{(aq)} \rightleftharpoons A^{2+}_{(aq)} + B_{(s)}$. Its $E^{\circ}$ is $1.0 \ V$. The $\Delta_{r}H^{\circ}$ of the reaction is $-163 \ kJ \ mol^{-1}$. What is $\Delta_{r}S^{\circ}$ (in $J \ K^{-1} \ mol^{-1}$) of the reaction? $(F = 96500 \ C \ mol^{-1})$

  • A
    $10$
  • B
    $100$
  • C
    $1000$
  • D
    $10000$

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If molar conductance at infinite dilution for $CH_3COO^-$ and $H^+$ ions are $50 \text{ S cm}^2 \text{mol}^{-1}$ and $350 \text{ S cm}^2 \text{mol}^{-1}$ respectively, and the molar conductivity of $5 \times 10^{-2} \text{ M}$ $CH_3COOH$ is $20 \text{ S cm}^2 \text{mol}^{-1}$, what is the hydrogen ion concentration in $\text{mol/dm}^3$ of $CH_3COOH$?

Which of the following statements is incorrect?

The conductivity of $0.001028 \, mol \, L^{-1}$ acetic acid is $4.95 \times 10^{-5} \, S \, cm^{-1}$. Calculate its dissociation constant if $\Lambda_m^\circ$ for acetic acid is $390.5 \, S \, cm^2 \, mol^{-1}$.

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Efficiency of the following cell is $84\%$. $A_{(s)} + B^{2+}(aq.) \rightleftharpoons A^{2+}(aq.) + B_{(s)}$; $\Delta H^o = -285 \ kJ$. Then the standard $EMF$ of the cell will be ........... $V$.

The molar conductivity of $0.027 \ M$ methanoic acid is $40.42 \ S \ cm^2 \ mol^{-1}$. The value of dissociation constant of this acid is
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