Define the following terms:
$(a)$ Activation energy
$(b)$ Activated complex

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(N/A) Activation energy: It is the minimum extra amount of energy absorbed by the reactant molecules so that their energy becomes equal to the threshold value,enabling them to undergo a chemical reaction.
$(b)$ Activated complex: It is an unstable intermediate species formed during the course of a chemical reaction,where the bonds of the reactants are partially broken and the bonds of the products are partially formed. It corresponds to the energy maximum on the potential energy profile.

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Which statement is incorrect for collision theory?

For the reaction $CH_{3}CH_{2}CH_{2}I + OH^{-} \rightarrow CH_{3}CH_{2}CH_{2}OH + I^{-}$,the rate constant is $1.84 \ (mol \ L^{-1})^{-1} \ min^{-1}$ at $27^{\circ}C$ $(300 \ K)$ and $38.84 \ (mol \ L^{-1})^{-1} \ min^{-1}$ at $327 \ K$. Calculate the activation energy $(E_{a})$ in $cal \ mol^{-1}$.

Which of the following statements is true about the equilibrium constant and rate constant of a single-step chemical reaction?

An increase in the concentration of the reactants of a reaction leads to a change in:

Assertion : According to transition state theory for the formation of an activated complex,one of the vibrational degrees of freedom is converted into a translational degree of freedom.
Reason : Energy of the activated complex is higher than the energy of reactant molecules.

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