Diborane is formed from the elements as shown in equation $(i)$:
$2 B_{(s)} + 3 H_{2(g)} \longrightarrow B_2H_{6(g)} \dots (i)$
Given that:
$H_2O_{(l)} \longrightarrow H_2O_{(g)}, \quad \Delta H_1^{\circ} = 44 \, kJ$
$2 B_{(s)} + \frac{3}{2} O_{2(g)} \longrightarrow B_2O_{3(s)}, \quad \Delta H_2^{\circ} = -1273 \, kJ$
$B_2H_{6(g)} + 3 O_{2(g)} \longrightarrow B_2O_{3(s)} + 3 H_2O_{(g)}, \quad \Delta H_3^{\circ} = -2035 \, kJ$
$H_{2(g)} + \frac{1}{2} O_{2(g)} \longrightarrow H_2O_{(l)}, \quad \Delta H_4^{\circ} = -286 \, kJ$
The $\Delta H^{\circ}$ for the reaction $(i)$ is $..... \, kJ$.
$2 B_{(s)} + 3 H_{2(g)} \longrightarrow B_2H_{6(g)} \dots (i)$
Given that:
$H_2O_{(l)} \longrightarrow H_2O_{(g)}, \quad \Delta H_1^{\circ} = 44 \, kJ$
$2 B_{(s)} + \frac{3}{2} O_{2(g)} \longrightarrow B_2O_{3(s)}, \quad \Delta H_2^{\circ} = -1273 \, kJ$
$B_2H_{6(g)} + 3 O_{2(g)} \longrightarrow B_2O_{3(s)} + 3 H_2O_{(g)}, \quad \Delta H_3^{\circ} = -2035 \, kJ$
$H_{2(g)} + \frac{1}{2} O_{2(g)} \longrightarrow H_2O_{(l)}, \quad \Delta H_4^{\circ} = -286 \, kJ$
The $\Delta H^{\circ}$ for the reaction $(i)$ is $..... \, kJ$.
- A$36$
- B$520$
- C$509$
- D$-3550$
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At constant pressure, the heat of formation of a compound is not dependent on temperature, when
DifficultWBJEE 2019
View SolutionCalculate the enthalpy change in $kJ$ for the reaction: $2C_{(graphite)} + 2H_{2(g)} \to C_2H_{4(g)}$
$C_{(graphite)} + O_{2(g)} \to CO_{2(g)} \quad \Delta H = -393.5 \ kJ$
$C_2H_{4(g)} + 3O_{2(g)} \to 2CO_{2(g)} + 2H_2O_{(l)} \quad \Delta H = -1410.9 \ kJ$
$H_{2(g)} + 1/2O_{2(g)} \to H_2O_{(l)} \quad \Delta H = -285.8 \ kJ$
$C_{(graphite)} + O_{2(g)} \to CO_{2(g)} \quad \Delta H = -393.5 \ kJ$
$C_2H_{4(g)} + 3O_{2(g)} \to 2CO_{2(g)} + 2H_2O_{(l)} \quad \Delta H = -1410.9 \ kJ$
$H_{2(g)} + 1/2O_{2(g)} \to H_2O_{(l)} \quad \Delta H = -285.8 \ kJ$
Medium
View SolutionConsider the following data:
$\Delta_{f}H^{\Theta}(CH_{4}, g) = -X \ kJ \ mol^{-1}$
Enthalpy of sublimation of graphite = $Y \ kJ \ mol^{-1}$
Dissociation enthalpy of $H_{2} = Z \ kJ \ mol^{-1}$
The bond enthalpy of $C-H$ bond is given by:
$\Delta_{f}H^{\Theta}(CH_{4}, g) = -X \ kJ \ mol^{-1}$
Enthalpy of sublimation of graphite = $Y \ kJ \ mol^{-1}$
Dissociation enthalpy of $H_{2} = Z \ kJ \ mol^{-1}$
The bond enthalpy of $C-H$ bond is given by:
DifficultJEE MAIN 2026
View SolutionUsing the data provided,calculate the bond energy $(kJ \ mol^{-1})$ of a $C \equiv C$ bond in $C_{2}H_{2}$. (Take the bond energy of a $C-H$ bond as $350 \ kJ \ mol^{-1}$)
$2C_{(s)} + H_{2(g)} \longrightarrow C_{2}H_{2(g)} \quad \Delta H = 225 \ kJ \ mol^{-1}$
$2C_{(s)} \longrightarrow 2C_{(g)} \quad \Delta H = 1410 \ kJ \ mol^{-1}$
$H_{2(g)} \longrightarrow 2H_{(g)} \quad \Delta H = 330 \ kJ \ mol^{-1}$
$2C_{(s)} + H_{2(g)} \longrightarrow C_{2}H_{2(g)} \quad \Delta H = 225 \ kJ \ mol^{-1}$
$2C_{(s)} \longrightarrow 2C_{(g)} \quad \Delta H = 1410 \ kJ \ mol^{-1}$
$H_{2(g)} \longrightarrow 2H_{(g)} \quad \Delta H = 330 \ kJ \ mol^{-1}$
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