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Answer the following questions based on the $P$ - $T$ phase diagram of carbon dioxide:
$(a)$ At what temperature and pressure can the solid,liquid and vapour phases of $CO_{2}$ co-exist in equilibrium?
$(b)$ What is the effect of decrease of pressure on the fusion and boiling point of $CO_{2}$?
$(c)$ What are the critical temperature and pressure for $CO_{2}$? What is their significance?
$(d)$ Is $CO_{2}$ solid,liquid or gas at $(i)$ $-70^{\circ}C$ under $1\;atm$,$(ii)$ $-60^{\circ}C$ under $10\;atm$,$(iii)$ $15^{\circ}C$ under $56\;atm$?

$A$ lead ball moving with a velocity $V$ strikes a wall and stops. If $50\%$ of its energy is converted into heat,then what will be the increase in temperature? (Specific heat of lead is $S$)

$A$ $10.0 \,W$ electrical heater is used to heat a container filled with $0.5 \,kg$ of water. It is found that the temperature of the water and the container rose by $3 \,K$ in $15 \,min$. The container is then emptied,dried,and filled with $2 \,kg$ of an oil. It is now observed that the same heater raises the temperature of the container-oil system by $2 \,K$ in $20 \,min$. Assuming no other heat losses in any of the processes,the specific heat capacity of the oil is ................ $\times 10^3 \,J K^{-1} kg^{-1}$.

$A$ glass flask of volume $1$ litre is fully filled with mercury at $0\,^{\circ}C$. Both the flask and mercury are now heated to $100\,^{\circ}C$. If the coefficient of volume expansion of mercury is $1.82 \times 10^{-4}/^{\circ}C$ and the coefficient of linear expansion of glass is $10 \times 10^{-6}/^{\circ}C$,the amount of mercury which is spilled out is ............ $ml$. (in $.2$)

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The heat required to convert $1 \, g$ of ice at $0^{\circ}C$ into steam at $100^{\circ}C$ is (given $L_{f} = 80 \, cal/g$,$c_{w} = 1 \, cal/g^{\circ}C$,$L_{v} = 536 \, cal/g$):

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