For which of the following liquid mixtures $\Delta_{\text{mix}}H=0$ and $\Delta_{\text{mix}}V=0$?

  • A
    Ethyl chloride,ethyl bromide
  • B
    Ethanol,acetone
  • C
    Phenol,aniline
  • D
    Chloroform,acetone

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Two liquids $X$ and $Y$ form an ideal solution. At $300 \ K,$ vapour pressure of the solution containing $1 \ mol$ of $X$ and $3 \ mol$ of $Y$ is $550 \ mm \ Hg.$ At the same temperature,if $1 \ mol$ of $Y$ is further added to this solution,vapour pressure of the solution increases by $10 \ mm \ Hg.$ Vapour pressure (in $mm \ Hg$) of $X$ and $Y$ in their pure states will be,respectively:

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