From the stability constant (hypothetical values) given below,predict which is the strongest ligand:

The molar ionic conductance of the octahedral complexes:
$(i)$ $PtCl_4 \cdot 5 NH_3$ $(ii)$ $PtCl_4 \cdot 4 NH_3$ $(iii)$ $PtCl_4 \cdot 3 NH_3$ $(iv)$ $PtCl_4 \cdot 2 NH_3$
Follow the order:

Calculate the overall complex dissociation equilibrium constant for the $Cu(NH_3)_4^{2+}$ ion,given that $\beta_4$ for this complex is $2.1 \times 10^{13}$.

The number of moles of $NH_{3}$ that must be added to $2 \, L$ of $0.80 \, M \, AgNO_{3}$ in order to reduce the concentration of $Ag^{+}$ ions to $5.0 \times 10^{-8} \, M$ ($K_{\text{formation}}$ for $[Ag(NH_{3})_{2}]^{+} = 1.0 \times 10^{8}$) is ...... . (Nearest integer)
[Assume no volume change on adding $NH_{3}$ ]

The aqueous solution of which of the following complexes has the least conductivity under identical conditions?

The stepwise formation of $[Cu(NH_{3})_{4}]^{2+}$ is given below:
$Cu^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})]^{2+} \quad K_{1}$
$[Cu(NH_{3})]^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})_{2}]^{2+} \quad K_{2}$
$[Cu(NH_{3})_{2}]^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})_{3}]^{2+} \quad K_{3}$
$[Cu(NH_{3})_{3}]^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})_{4}]^{2+} \quad K_{4}$
The values of stability constants $K_{1}, K_{2}, K_{3}$ and $K_{4}$ are $10^{4}, 1.58 \times 10^{3}, 5 \times 10^{2}$ and $10^{2}$ respectively. The overall equilibrium constant for dissociation of $[Cu(NH_{3})_{4}]^{2+}$ is $x \times 10^{-12}$. The value of $x$ is ...............
(Rounded off to the nearest integer)