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Who synthesized the first organic compound,urea,in the laboratory?

Based on the structures $P$, $Q$, and $R$ defined as $P = OHC-CH_2-CH=CH-CH_2-CHO$, $Q = HO-CH_2-CH_2-CH_2-CH_2-CH_2-CH_2-OH$, and $R = HO-CH_2-CH_2-CH=CH-CH_2-CHO$, which of the following statements is correct?

The product formed by heating a mixture of ammonium chloride and potassium cyanate is:

On mixing tetraethyl lead to gasoline available at petrol pumps,

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Allyl isocyanide has:

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