How will you convert:
$(i)$ Ethanoic acid into methanamine
$(ii)$ Hexanenitrile into $1$-aminopentane
$(iii)$ Methanol to ethanoic acid
$(iv)$ Ethanamine into methanamine
$(v)$ Ethanoic acid into propanoic acid
$(vi)$ Methanamine into ethanamine
$(vii)$ Nitromethane into dimethylamine
$(viii)$ Propanoic acid into ethanoic acid?
$(i)$ Ethanoic acid into methanamine
$(ii)$ Hexanenitrile into $1$-aminopentane
$(iii)$ Methanol to ethanoic acid
$(iv)$ Ethanamine into methanamine
$(v)$ Ethanoic acid into propanoic acid
$(vi)$ Methanamine into ethanamine
$(vii)$ Nitromethane into dimethylamine
$(viii)$ Propanoic acid into ethanoic acid?
(N/A) $(i)$ $\text{CH}_3\text{COOH}$ $\xrightarrow{\text{SOCl}_2} \text{CH}_3\text{COCl}$ $\xrightarrow{\text{NH}_3} \text{CH}_3\text{CONH}_2$ $\xrightarrow{\text{Br}_2/\text{NaOH}} \text{CH}_3\text{NH}_2$
$(ii)$ $\text{C}_5\text{H}_{11}\text{CN}$ $\xrightarrow{\text{H}^+/\text{H}_2\text{O}} \text{C}_5\text{H}_{11}\text{COOH}$ $\xrightarrow{\text{SOCl}_2} \text{C}_5\text{H}_{11}\text{COCl}$ $\xrightarrow{\text{NH}_3} \text{C}_5\text{H}_{11}\text{CONH}_2$ $\xrightarrow{\text{Br}_2/\text{KOH}} \text{C}_5\text{H}_{11}\text{NH}_2$
$(iii)$ $\text{CH}_3\text{OH}$ $\xrightarrow{\text{PCl}_5} \text{CH}_3\text{Cl}$ $\xrightarrow{\text{KCN}} \text{CH}_3\text{CN}$ $\xrightarrow{\text{H}^+/\text{H}_2\text{O}} \text{CH}_3\text{COOH}$
$(iv)$ $\text{CH}_3\text{CH}_2\text{NH}_2$ $\xrightarrow{\text{NaNO}_2/\text{HCl}} \text{CH}_3\text{CH}_2\text{OH}$ $\xrightarrow{\text{KMnO}_4} \text{CH}_3\text{COOH}$ $\xrightarrow{\text{NH}_3, \Delta} \text{CH}_3\text{CONH}_2$ $\xrightarrow{\text{Br}_2/\text{NaOH}} \text{CH}_3\text{NH}_2$
$(v)$ $\text{CH}_3\text{COOH}$ $\xrightarrow{\text{LiAlH}_4} \text{CH}_3\text{CH}_2\text{OH}$ $\xrightarrow{\text{PCl}_5} \text{CH}_3\text{CH}_2\text{Cl}$ $\xrightarrow{\text{KCN}} \text{CH}_3\text{CH}_2\text{CN}$ $\xrightarrow{\text{H}^+/\text{H}_2\text{O}} \text{CH}_3\text{CH}_2\text{COOH}$
$(vi)$ $\text{CH}_3\text{NH}_2$ $\xrightarrow{\text{NaNO}_2/\text{HCl}} \text{CH}_3\text{OH}$ $\xrightarrow{\text{PCl}_5} \text{CH}_3\text{Cl}$ $\xrightarrow{\text{KCN}} \text{CH}_3\text{CN}$ $\xrightarrow{\text{H}_2/\text{Ni}} \text{CH}_3\text{CH}_2\text{NH}_2$
$(vii)$ $\text{CH}_3\text{NO}_2$ $\xrightarrow{\text{Sn/HCl}} \text{CH}_3\text{NH}_2$ $\xrightarrow{\text{CHCl}_3/\text{KOH}} \text{CH}_3\text{NC}$ $\xrightarrow{\text{Na/C}_2\text{H}_5\text{OH}} \text{CH}_3\text{NHCH}_3$
$(viii)$ $\text{CH}_3\text{CH}_2\text{COOH}$ $\xrightarrow{\text{NH}_3, \Delta} \text{CH}_3\text{CH}_2\text{CONH}_2$ $\xrightarrow{\text{Br}_2/\text{KOH}} \text{CH}_3\text{CH}_2\text{NH}_2$ $\xrightarrow{\text{NaNO}_2/\text{HCl}} \text{CH}_3\text{CH}_2\text{OH}$ $\xrightarrow{\text{KMnO}_4} \text{CH}_3\text{COOH}$
$(ii)$ $\text{C}_5\text{H}_{11}\text{CN}$ $\xrightarrow{\text{H}^+/\text{H}_2\text{O}} \text{C}_5\text{H}_{11}\text{COOH}$ $\xrightarrow{\text{SOCl}_2} \text{C}_5\text{H}_{11}\text{COCl}$ $\xrightarrow{\text{NH}_3} \text{C}_5\text{H}_{11}\text{CONH}_2$ $\xrightarrow{\text{Br}_2/\text{KOH}} \text{C}_5\text{H}_{11}\text{NH}_2$
$(iii)$ $\text{CH}_3\text{OH}$ $\xrightarrow{\text{PCl}_5} \text{CH}_3\text{Cl}$ $\xrightarrow{\text{KCN}} \text{CH}_3\text{CN}$ $\xrightarrow{\text{H}^+/\text{H}_2\text{O}} \text{CH}_3\text{COOH}$
$(iv)$ $\text{CH}_3\text{CH}_2\text{NH}_2$ $\xrightarrow{\text{NaNO}_2/\text{HCl}} \text{CH}_3\text{CH}_2\text{OH}$ $\xrightarrow{\text{KMnO}_4} \text{CH}_3\text{COOH}$ $\xrightarrow{\text{NH}_3, \Delta} \text{CH}_3\text{CONH}_2$ $\xrightarrow{\text{Br}_2/\text{NaOH}} \text{CH}_3\text{NH}_2$
$(v)$ $\text{CH}_3\text{COOH}$ $\xrightarrow{\text{LiAlH}_4} \text{CH}_3\text{CH}_2\text{OH}$ $\xrightarrow{\text{PCl}_5} \text{CH}_3\text{CH}_2\text{Cl}$ $\xrightarrow{\text{KCN}} \text{CH}_3\text{CH}_2\text{CN}$ $\xrightarrow{\text{H}^+/\text{H}_2\text{O}} \text{CH}_3\text{CH}_2\text{COOH}$
$(vi)$ $\text{CH}_3\text{NH}_2$ $\xrightarrow{\text{NaNO}_2/\text{HCl}} \text{CH}_3\text{OH}$ $\xrightarrow{\text{PCl}_5} \text{CH}_3\text{Cl}$ $\xrightarrow{\text{KCN}} \text{CH}_3\text{CN}$ $\xrightarrow{\text{H}_2/\text{Ni}} \text{CH}_3\text{CH}_2\text{NH}_2$
$(vii)$ $\text{CH}_3\text{NO}_2$ $\xrightarrow{\text{Sn/HCl}} \text{CH}_3\text{NH}_2$ $\xrightarrow{\text{CHCl}_3/\text{KOH}} \text{CH}_3\text{NC}$ $\xrightarrow{\text{Na/C}_2\text{H}_5\text{OH}} \text{CH}_3\text{NHCH}_3$
$(viii)$ $\text{CH}_3\text{CH}_2\text{COOH}$ $\xrightarrow{\text{NH}_3, \Delta} \text{CH}_3\text{CH}_2\text{CONH}_2$ $\xrightarrow{\text{Br}_2/\text{KOH}} \text{CH}_3\text{CH}_2\text{NH}_2$ $\xrightarrow{\text{NaNO}_2/\text{HCl}} \text{CH}_3\text{CH}_2\text{OH}$ $\xrightarrow{\text{KMnO}_4} \text{CH}_3\text{COOH}$
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Similar Questions
Match List-$I$ with List-$II$ :
List-$I$ List-$II$ $a$. Gabriel synthesis $i$. Benzaldehyde $b$. Kolbe synthesis $ii$. Ethers $c$. Williamson synthesis $iii$. Primary amines $d$. Etard reaction $iv$. Salicylic acid
Choose the correct answer from the options given below :
| List-$I$ | List-$II$ |
| $a$. Gabriel synthesis | $i$. Benzaldehyde |
| $b$. Kolbe synthesis | $ii$. Ethers |
| $c$. Williamson synthesis | $iii$. Primary amines |
| $d$. Etard reaction | $iv$. Salicylic acid |
Choose the correct answer from the options given below :
MediumNEET 2022
View SolutionMatch the following:
List-$I$ List-$II$ $A$. Amide $I$. Carbylamine reaction $B$. Nitrile $II$. Hinsberg's reagent $C$. $C_6H_5SO_2Cl$ $III$. Hofmann's bromamide reaction $D$. $1^{\circ}$-Amine $IV$. $LiAlH_4$
| List-$I$ | List-$II$ |
|---|---|
| $A$. Amide | $I$. Carbylamine reaction |
| $B$. Nitrile | $II$. Hinsberg's reagent |
| $C$. $C_6H_5SO_2Cl$ | $III$. Hofmann's bromamide reaction |
| $D$. $1^{\circ}$-Amine | $IV$. $LiAlH_4$ |
DifficultTS EAMCET 2022
View SolutionWhich one of the following reaction sequences will give an azo dye?
Match each of the compounds in Column $I$ with its characteristic reaction$(s)$ in Column $II$.
Column $I$ Column $II$ $A$. $CH_3CH_2CH_2CN$ $p$. Reduction with $Pd-C/H_2$ $B$. $CH_3CH_2OCOCH_3$ $q$. Reduction with $SnCl_2/HCl$ $C$. $CH_3-CH=CH-CH_2OH$ $r$. Development of foul smell on treatment with chloroform and alcoholic $KOH$ $D$. $CH_3CH_2CH_2CH_2NH_2$ $s$. Reduction with diisobutylaluminium hydride $(DIBAL-H)$ $t$. Alkaline hydrolysis
| Column $I$ | Column $II$ |
|---|---|
| $A$. $CH_3CH_2CH_2CN$ | $p$. Reduction with $Pd-C/H_2$ |
| $B$. $CH_3CH_2OCOCH_3$ | $q$. Reduction with $SnCl_2/HCl$ |
| $C$. $CH_3-CH=CH-CH_2OH$ | $r$. Development of foul smell on treatment with chloroform and alcoholic $KOH$ |
| $D$. $CH_3CH_2CH_2CH_2NH_2$ | $s$. Reduction with diisobutylaluminium hydride $(DIBAL-H)$ |
| $t$. Alkaline hydrolysis |
$E \xleftarrow{KOH/Br_2} D \xleftarrow{H_2O_2/OH^{-} \atop (Partial \ Hydrolysis)} C \xleftarrow{NaCN} C_2H_5-Cl$ $\xrightarrow{AgCN} A$ $\xrightarrow{LiAlH_4} B$
What is the relationship between $B$ and $E$?
What is the relationship between $B$ and $E$?
Medium
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