The hydrated $Cu^{2+}$ ion is:

Which of the following is a low-spin complex?

Given below are two statements:
Statement $I$ : $N(CH_3)_3$ and $P(CH_3)_3$ can act as ligands to form transition metal complexes.
Statement $II$: As $N$ and $P$ are from same group,the nature of bonding of $N(CH_3)_3$ and $P(CH_3)_3$ is always same with transition metals.
In the light of the above statements,choose the most appropriate answer from the options given below:

The stepwise formation of $[Cu(NH_{3})_{4}]^{2+}$ is given below:
$Cu^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})]^{2+} \quad K_{1}$
$[Cu(NH_{3})]^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})_{2}]^{2+} \quad K_{2}$
$[Cu(NH_{3})_{2}]^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})_{3}]^{2+} \quad K_{3}$
$[Cu(NH_{3})_{3}]^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})_{4}]^{2+} \quad K_{4}$
The values of stability constants $K_{1}, K_{2}, K_{3}$ and $K_{4}$ are $10^{4}, 1.58 \times 10^{3}, 5 \times 10^{2}$ and $10^{2}$ respectively. The overall equilibrium constant for dissociation of $[Cu(NH_{3})_{4}]^{2+}$ is $x \times 10^{-12}$. The value of $x$ is ...............
(Rounded off to the nearest integer)

$A$ first row transition metal $(M)$ does not liberate $H_{2}$ gas from dilute $HCl$. $1 \ mol$ of aqueous solution of $MSO_{4}$ is treated with excess of aqueous $KCN$ and then $H_{2}S_{(g)}$ is passed through the solution. The amount of $MS$ (metal sulphide) formed from the above reaction is . . . . . . $mol$.

Which of the following coordination compounds acts as a non-electrolyte in solution?