In an acid-base titration,$0.1 \ M \ HCl$ solution was added to the $NaOH$ solution of unknown strength. Which of the following correctly shows the change of $pH$ of the titration mixture in this experiment?

In a conductometric titration,a small volume of titrant of higher concentration is added stepwise to a larger volume of titrate of much lower concentration,and the conductance is measured after each addition.
The limiting ionic conductivity ( $\Lambda ^0$ ) values (in $mS \ m ^2 \ mol ^{-1}$ ) for different ions in aqueous solutions are given below:

Ions	$Ag ^{+}$	$K ^{+}$	$Na ^{+}$	$H ^{+}$	$NO _3^{-}$	$Cl ^{-}$	$SO _4^{2-}$	$OH ^{-}$	$CH _3COO ^{-}$
$\Lambda _0$	$6.2$	$7.4$	$5.0$	$35.0$	$7.2$	$7.6$	$16.0$	$19.9$	$4.1$

For different combinations of titrates and titrants given in List-$I$,the graphs of 'conductance' versus 'volume of titrant' are given in List-$II$.

List-$I$	List-$II$
$(P)$ Titrate: $KCl$,Titrant: $AgNO _3$	$(1)$ Graph showing initial decrease then increase
$(Q)$ Titrate: $AgNO _3$,Titrant: $KCl$	$(2)$ Graph showing sharp decrease then sharp increase
$(R)$ Titrate: $NaOH$,Titrant: $HCl$	$(3)$ Graph showing slight decrease then increase
$(S)$ Titrate: $NaOH$,Titrant: $CH _3COOH$	$(4)$ Graph showing continuous increase
	$(5)$ Graph showing decrease then constant

Match each entry in List-$I$ with the appropriate entry in List-$II$ and choose the correct option.

When $10 \ mL$ of an aqueous solution of $Fe^{2+}$ ions was titrated in the presence of dil $H_{2}SO_{4}$ using diphenylamine indicator,$15 \ mL$ of $0.02 \ M$ solution of $K_{2}Cr_{2}O_{7}$ was required to get the end point. The molarity of the solution containing $Fe^{2+}$ ions is $X \times 10^{-2} \ M$. The value of $x$ is $....$ (Nearest integer)

Which of the following titrations is methyl orange the best indicator for?

Consider the titration of $NaOH$ solution versus $1.25\, M$ oxalic acid solution. At the end point,the following burette readings were obtained:
$(i)$ $4.5\, mL$ $\quad (ii)$ $4.5\, mL$ $\quad (iii)$ $4.4\, mL$
$(iv)$ $4.4\, mL$ $\quad (v)$ $4.4\, mL$
If the volume of oxalic acid taken was $10.0\, mL$,then the molarity of the $NaOH$ solution is .... $M$ (Rounded-off to the nearest integer).

For standardizing $NaOH$ solution,which of the following is used as a primary standard?