In Lassaigne's extract of an organic compound,both nitrogen and sulphur are present,which gives blood red colour with $Fe^{3+}$ due to the formation of-

  • A
    $[Fe(SCN)]^{2+}$
  • B
    $Fe_4[Fe(CN)_6]_3 \cdot xH_2O$
  • C
    $NaSCN$
  • D
    $[Fe(CN)_5NOS]^{4-}$

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During the halogen test,the sodium fusion extract is boiled with concentrated $HNO_3$ to ... .

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Column $I$ Column $II$
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$B$. Benzene sulfonic acid $ii$. Violet colour with sodium nitroprusside
$C$. Thiourea $iii$. Blue colour with hot and acidic solution of $FeSO_4$

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$A$ solution of $m-$chloroaniline,$m-$chlorophenol and $m-$chlorobenzoic acid in ethyl acetate was extracted initially with a saturated solution of $NaHCO_3$ to give fraction $A$. The left over organic phase was extracted with dilute $NaOH$ solution to give fraction $B$. The final organic layer was labelled as fraction $C$. Fractions $A$,$B$ and $C$ contain respectively

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