In the Dumas method,$1 \ g$ of an organic compound gives $50 \ mL$ of $N_2$ gas at $300 \ K$ and $740 \ mm \ Hg$ pressure. If the aqueous tension at $300 \ K$ is $15 \ mm \ Hg$,what is the percentage of nitrogen in the compound?

  • A
    $5.42$
  • B
    $10.84$
  • C
    $21.68$
  • D
    $2.71$

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Why is a solution of potassium hydroxide used to absorb carbon dioxide evolved during the estimation of carbon present in an organic compound?

In the $Kjeldahl$ method,when an organic compound containing nitrogen is heated with concentrated $H_2SO_4$,nitrogen is converted into which of the following?

When $0.15 \ g$ of an organic compound was analyzed using the Carius method for the estimation of bromine,$0.2397 \ g$ of $AgBr$ was obtained. The percentage of bromine in the organic compound is $.....$ (Nearest integer).
[Atomic mass: Silver $= 108$,Bromine $= 80$]

Match column $-I$ and column $-II$ with the correct relation:
Column $-I$ Column $-II$
$(i)$ Dumas method $(a)$ Absorption of $NH_3$ in $H_2SO_4$
$(ii)$ Kjeldahl's method $(b)$ $BaCl_2$ by added $BaSO_4$
$(iii)$ Carius method $(c)$ Mixture of Magnesia
$(iv)$ Estimation of phosphorus $(d)$ $N_2$

State True or False for the following statements:
$(i)$ The volume of $N_2$ is measured by nitrometer.
$(ii)$ The weight of $N_2$ is measured by nitrometer.
$(iii)$ The weight of $NH_3$ is measured by nitrometer.
$(iv)$ The volume of $NH_3$ is measured by nitrometer.

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