When $0.15 \ g$ of an organic compound was analyzed using the Carius method for the estimation of bromine,$0.2397 \ g$ of $AgBr$ was obtained. The percentage of bromine in the organic compound is $.....$ (Nearest integer).
[Atomic mass: Silver $= 108$,Bromine $= 80$]

  • A
    $96$
  • B
    $12$
  • C
    $85$
  • D
    $68$

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Differentiate between the principle of estimation of nitrogen in an organic compound by $(i)$ Dumas method and $(ii)$ Kjeldahl's method.

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$0.25 \ g$ of an organic compound containing chlorine gave $0.40 \ g$ of silver chloride in Carius estimation. The percentage of chlorine present in the compound is $.....$ [in nearest integer].
(Given: Molar mass of $Ag$ is $108 \ g \ mol^{-1}$ and that of $Cl$ is $35.5 \ g \ mol^{-1}$)

$A$ sample of $0.125 \ g$ of an organic compound when analysed by Duma's method yields $22.78 \ mL$ of nitrogen gas collected over $KOH$ solution at $280 \ K$ and $759 \ mm \ Hg$. The percentage of nitrogen in the given organic compound is (Nearest integer).
$(a)$ The vapour pressure of water at $280 \ K$ is $14.2 \ mm \ Hg$
$(b)$ $R = 0.082 \ L \ atm \ K^{-1} \ mol^{-1}$

In Kjeldahl's method for the estimation of nitrogen,the formula used is

Which element is estimated by the Carius method?

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