In the following reactions,products $A$ and $B$ are

  • A
    $A = \text{3-hydroxy-6,6-dimethylcyclohexanone}; B = \text{6,6-dimethylcyclohex-2-enone}$
  • B
    $A = \text{3-hydroxy-2,2-dimethylcyclohexanone}; B = \text{6,6-dimethylcyclohex-2-enone}$
  • C
    $A = \text{2-hydroxy-2,3-dimethylcyclobutanecarbaldehyde}; B = \text{2,3-dimethylcyclobut-2-enecarbaldehyde}$
  • D
    $A = \text{2-hydroxy-2,3-dimethylcyclobutanecarbaldehyde}; B = \text{2-methylene-3,3-dimethylcyclobutanecarbaldehyde}$

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Draw structures of the following derivatives:
$(i)$ The $2,4-$dinitrophenylhydrazone of benzaldehyde
$(ii)$ Cyclopropanone oxime
$(iii)$ Acetaldehyde dimethyl acetal
$(iv)$ The semicarbazone of cyclobutanone
$(v)$ The ethylene ketal of hexan$-3-$one
$(vi)$ The methyl hemiacetal of formaldehyde

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Explain the different oxidation reactions of aldehydes and ketones.

Provide the chemical conversion for the following:
$(i)$ $3-$phenylprop$-2-$enal from Benzaldehyde and Ethanal (Cross-Aldol Condensation).
$(ii)$ Benzyl alcohol from Benzene.

$A$ primary alcohol was reacted with pyridinium chlorochromate $(PCC)$,which resulted in a product $P$. The product $P$ on treatment with ammoniacal silver nitrate solution produces:

The active ion in Tollen's reagent is

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